Deconvoluting the Optical Response of Biocompatible Photonic Pigments

To unlock the widespread use of block copolymers as photonic pigments, there is an urgent need to consider their environmental impact (cf. microplastic pollution). Here we show how an inverse photonic glass architecture can enable the use of biocompatible bottlebrush block copolymers (BBCPs), which otherwise lack the refractive index contrast needed for a strong photonic response. A library of photonic pigments is produced from poly(norbornene-graft-polycaprolactone)-block-poly(norbornene-graft-polyethylene glycol), with the color tuned via either the BBCP molecular weight or the processing temperature upon microparticle fabrication. The structure-optic relationship between the 3D porous morphology of the microparticles and their complex optical response is revealed by both an analytical scattering model and 3D finite-difference time domain (FDTD) simulations. Combined, this allows for strategies to enhance the color purity to be proposed and realized with our biocompatible BBCP system.

Automated summary

This study demonstrates how an inverse photonic glass architecture enables the use of biocompatible bottlebrush block copolymers (BBCPs) as photonic pigments. A library of photonic pigments is produced by adjusting the BBCP molecular weight or processing temperature. The relationship between the microparticles' 3D porous morphology and their optical response is analyzed, allowing strategies to enhance color purity to be proposed and realized with the biocompatible BBCP system.