☆ 4.8 Article

Revealing the Role of the Cyaphide Ion as a Bridging Ligand in Heterometallic Complexes

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Related references

Note: Only part of the references are listed.

Article Chemistry, Multidisciplinary

Case Study of N-iPr versus N-Mes Substituted NHC Ligands in Nickel Chemistry: The Coordination and Cyclotrimerization of Alkynes at [Ni(NHC)2]

Lukas Tendera et al.

Summary: This study investigates the effects of two different NHC ligands in complexes [Ni(NHC)(2)] and their behavior towards alkynes. Complex 2 demonstrated efficient catalytic activity for the cyclotrimerization of various alkynes at ambient conditions, while complex 1(Me) showed lower catalytic performance. The higher stability of N-alkyl substituted NHC complex is attributed to better electron transfer and enhanced backbonding.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Photochemical C(sp)-C(sp2) Bond Activation in Phosphaalkynes: A New Route to Reactive Terminal Cyaphido Complexes LnM-CP

Tim Goelich et al.

Summary: The photochemical activation selectively leads to the formation of coordination compounds of the type LnPt(aryl)(C P) in Pt(0)-eta(2)-aryl-phosphaalkyne complexes, and the subsequent oxidative addition reaction is a novel and clean route for the synthesis of reactive terminal Pt(II)-cyaphido complexes. The thermodynamically uphill C-C bond cleavage reaction can be reversed upon heating, leading to quantitative reductive elimination towards the Pt(0)-phosphaalkyne-pi-complex.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

A Cyaphide Transfer Reagent

Daniel W. N. Wilson et al.

Summary: The cyanide ion plays a key role in industrially relevant chemical processes, but heavier cyanide analogues are largely unexplored due to a lack of suitable synthesis methods.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Electron Transfer in the Cs⊂{Mn4Fe4} Cubic Switch: a Soluble Molecular Model of the MnFe Prussian-Blue Analogues

Juan-Ramon Jimenez et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Metal-only Lewis Pairs of Rhodium with s, p and d-Block Metals

Sonia Bajo et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Controlled Reactivity of Terminal Cyaphide Complexes: Isolation of the 5-Coordinate [Ru(dppe)2(CP)]+

Madeleine C. Levis et al.

INORGANIC CHEMISTRY (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Strong π-Backbonding Enables Record Magnetic Exchange Coupling Through Cyanide

Juan A. Valdez-Moreira et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Formation of a Uranium-Bound η1-Cyaphide (CP-) Ligand via Activation and C-O Bond Cleavage of Phosphaethynolate (OCP-)

Christopher J. Hoerger et al.

ORGANOMETALLICS (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Metal-to-Metal Electron Transfer in Co/Fe Prussian Blue Molecular Analogues: The Ultimate Miniaturization

Evangelia S. Koumousi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Add to Collection

Article Chemistry, Multidisciplinary

Highly Chemoselective Carbon-Carbon σ-Bond Activation: Nickel/Lewis Acid Catalyzed Polyfluoroarylcyanation of Alkynes

Yasunori Minami et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

Add to Collection

Article Chemistry, Physical

Long-Range Corrected Hybrid Density Functionals with Improved Dispersion Corrections

You-Sheng Lin et al.

JOURNAL OF CHEMICAL THEORY AND COMPUTATION (2013)

Add to Collection

Article Chemistry, Multidisciplinary

A N-heterocyclic carbene gold hydroxide complex: a golden synthon

Sylvain Gaillard et al.

CHEMICAL COMMUNICATIONS (2010)

Add to Collection

Article Chemistry, Multidisciplinary

Molecular Double-Bond Covalent Radii for Elements Li-E112

Pekka Pyykko et al.

CHEMISTRY-A EUROPEAN JOURNAL (2009)

Add to Collection

Review Chemistry, Physical

All-electron scalar relativistic basis sets for third-row transition metal atoms

Dimitrios A. Pantazis et al.

JOURNAL OF CHEMICAL THEORY AND COMPUTATION (2008)

Add to Collection

Review Chemistry, Physical

Geometries of third-row transition-metal complexes from density-functional theory

Michael Buehl et al.

JOURNAL OF CHEMICAL THEORY AND COMPUTATION (2008)

Add to Collection

Article Chemistry, Physical

Bond orbitals from chemical valence theory

Artur Michalak et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2008)

Add to Collection

Article Biochemistry & Molecular Biology

Natural orbitals for chemical valence as descriptors of chemical bonding in transition metal complexes

Mariusz Mitoraj et al.

JOURNAL OF MOLECULAR MODELING (2007)

Add to Collection

Article Chemistry, Inorganic & Nuclear

A mononuclear eta(2)-bonded phosphaalkyne nickel(0) complex

Thomas Schaub et al.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE (2006)

Add to Collection

Article Chemistry, Multidisciplinary

Making the true CP ligand

Joseph G. Cordaro et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2006)

Add to Collection

Review Chemistry, Multidisciplinary

Triple-bond covalent radii

P Pyykkö et al.

CHEMISTRY-A EUROPEAN JOURNAL (2005)

Add to Collection

© Peeref 2019-2024. All rights reserved.