Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 61, Issue 42, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202208743
Keywords
Anode; Electrolyte Interface; Electrode Potential; Lithium Batteries; Solid Electrolyte Interphase; Structure Evolution
Categories
Funding
- National Key Research and Development Program [2021YFB2500300, 2021YFB2400300]
- National Natural Science Foundation of China [52103342, 22109007, U1801257]
- China Postdoctoral Science Foundation [BX2021136, 2021M700404, 2021M691712]
- Beijing Municipal Natural Science Foundation [Z200011]
- Tsinghua National Laboratory for Information Science and Technology for theoretical simulations
- Beijing Institute of Technology Research Fund Program for Young Scholars
- Analysis Center of Tsinghua University
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This study investigates the influence of electrode potential and anode material on the structural evolution of solid electrolyte interphase (SEI) in rechargeable lithium batteries, using both theoretical and experimental approaches. The results show that electrode potential plays a crucial role in determining the SEI structure, while the anode material has minimal impact. This research provides important insights for the rational regulation of SEI structure.
The performance of rechargeable lithium (Li) batteries is highly correlated with the structure of solid electrolyte interphase (SEI). The properties of a working anode are vital factors in determining the structure of SEI; however, the correspondingly poor understanding hinders the rational regulation of SEI. Herein, the electrode potential and anode material, two critical properties of an anode, in dictating the structural evolution of SEI were investigated theoretically and experimentally. The anode potential is identified as a crucial role in dictating the SEI structure. The anode potential determines the reduction products in the electrolyte, ultimately giving rise to the mosaic and bilayer SEI structure at high and low potential, respectively. In contrast, the anode material does not cause a significant change in the SEI structure. This work discloses the crucial role of electrode potential in dictating SEI structure and provides rational guidance to regulate SEI structure.
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