Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 61, Issue 34, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202207512
Keywords
Electrocatalysts; Hydrogen Evolution Reaction; Interface Engineering; Metallene
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Funding
- National Natural Science Foundation of China [12034002, 51872116]
- Jilin Province Science and Technology Development Program [20210301009GX]
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This study reports the synthesis of atomically dispersed MoOx species anchored on Rh metallene, achieving maximum exposure of the oxide-metal interface and resulting in a catalyst with ultrahigh alkaline HER activity.
Accelerating slow water dissociation kinetics is key to boosting the hydrogen evolution reaction (HER) in alkaline media. We report the synthesis of atomically dispersed MoOx species anchored on Rh metallene using a one-pot solvothermal method. The resulting structures expose the oxide-metal interfaces to the maximum extent. This leads to a MoOx-Rh catalyst with ultrahigh alkaline HER activity. We obtained a mass activity of 2.32 A mg(Rh)(-1) at an overpotential of 50 mV, which is 11.8 times higher than that of commercial Pt/C and surpasses the previously reported Rh-based electrocatalysts. First-principles calculations demonstrate that the interface between MoOx and Rh is the active center for alkaline HER. The MoOx sites preferentially adsorb and dissociate water molecules, and adjacent Rh sites adsorb the generated atomic hydrogen for efficient H-2 evolution. Our findings illustrate the potential of atomic interface engineering strategies in electrocatalysis.
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