4.8 Article

Gauging Radical Stabilization with Carbenes

Related references

Note: Only part of the references are listed.
Article Chemistry, Multidisciplinary

Access to a Labile Monomeric Magnesium Radical by Ball-Milling

Dawid Jedrzkiewicz et al.

Summary: This research focuses on the study of magnesium radicals and successfully isolates a monometallic magnesium radical. The crystal structure of the low-valent magnesium-iodine complex reveals strong bonding between magnesium and the ligand. Calculations show similar metal-to-CAAC charge transfer in different complexes.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Article Chemistry, Multidisciplinary

Organic Four-Electron Redox Systems Based on Bipyridine and Phenanthroline Carbene Architectures

Patrick W. Antoni et al.

Summary: This article presents a simple strategy to transform well-known two-electron redox active bipyridine and phenanthroline structures into strongly reducing four-electron redox systems, exhibiting multistage reversible redox behavior and strong polyelectrochromic properties.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Article Chemistry, Multidisciplinary

Isolation of Stable Borepin Radicals and Anions

Kimberly K. Hollister et al.

Summary: In this study, the first isolable, crystalline borepin radical and anion complexes were reported. These complexes were synthesized through the reduction of carbon-carbon double bonds in cyclic(alkyl)(amino) carbene-dibenzo[b,d]borepin precursors using potassium graphite. The resulting compounds have potential applications in the development of new materials and optoelectronics.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Article Chemistry, Multidisciplinary

The oxidation state in low-valent beryllium and magnesium compounds

Marti Gimferrer et al.

Summary: This article discusses the electronic structure of Lewis base-stabilized Be and Mg compounds and provides an explanation for their proposed oxidation states. The experimentally accomplished compounds rely on increasing the π-acidity of the ligand to strengthen the chemical bonds, and it is suggested that avoiding this interaction could lead to the presence of low-oxidation states.

CHEMICAL SCIENCE (2022)

Article Chemistry, Organic

A Bottleable Imidazole-Based Radical as a Single Electron Transfer Reagent

Arpan Das et al.

Summary: The study successfully synthesized and characterized an imidazole-based radical 2, which was proven to be a single electron transfer reagent and utilized as an organic electron donor in various organic transformations under ambient conditions.

JOURNAL OF ORGANIC CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Directed Design of a AuI Complex with a Reduced Mesoionic Carbene Radical Ligand: Insights from 1,2,3-Triazolylidene Selenium Adducts and Extensive Electrochemical Investigations

Julia Beerhues et al.

Summary: Extensive electrochemical investigations on 1,2,3-triazolylidene selenium adducts revealed a correlation between their reduction potentials and molecular structures. Unexpected quasi-reversibility was discovered in the reduction of two triazoline selones. Through spectroelectrochemical studies and calculations, the radical anion was successfully assigned to be triazoline centered, providing design principles for stabilizing radicals based on MICs.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Article Chemistry, Physical

r2SCAN-3c: A Swiss army knife composite electronic-structure method

Stefan Grimme et al.

Summary: The r(2)SCAN-3c method shows impressive performance in comprehensive tests, outperforming previous methods at a lower cost and becoming the new default in standard applications for systems with up to several hundreds of atoms.

JOURNAL OF CHEMICAL PHYSICS (2021)

Article Chemistry, Multidisciplinary

Highly Stable 1,2-Dicarbonyl Radical Cations Derived from N-Heterocyclic Carbenes

Youngsuk Kim et al.

Summary: This study presents the design and synthesis of a novel organic radical based on a 1,2-dicarbonyl scaffold supported by N-heterocyclic carbenes (NHCs), which exhibits remarkable stability due to the steric and electronic stabilization provided by the two NHC moieties. The radical cations can tolerate various harsh conditions and surpass the stability of triphenylmethyl and TEMPO radicals.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Multidisciplinary

Synergistic Catalysis by Bronsted Acid/Carbodicarbene Mimicking Frustrated Lewis Pair-Like Reactivity

Yi-Chen Chan et al.

Summary: By utilizing benzyl alcohol as a co-modulator, carbodicarbene is transformed into a Frustrated Lewis Pair-like reactivity, showing enhanced catalytic activity in various chemical reactions. This unique catalytic reactivity differs significantly from conventional NHC carbenes, demonstrating a new approach in diversifying FLP reactivity with the use of co-modulators.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Tuning the π-Accepting Properties of Mesoionic Carbenes: A Combined Computational and Experimental Study

Zhaowen Dong et al.

Summary: The study found that mesoionic imidazolylidenes bearing a diphenyltriazinyl (Dpt) substituent exhibit improved pi-acidic properties compared to Arduengo-type N-heterocyclic carbenes. This discovery was supported by computational analysis and experimental evidence. The new carbene was utilized to stabilize a low-valent paramagnetic tin compound, demonstrating its usefulness.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Article Multidisciplinary Sciences

Aryl radical-mediated N-heterocyclic carbene catalysis

Yuki Matsuki et al.

Summary: This article discusses the successful application of NHC-catalyzed aryl radical reactions in various arylations. The method allows for the generation of aryl radicals from halides through single electron transfer processes, providing a metal-free approach for radical reactions.

NATURE COMMUNICATIONS (2021)

Review Chemistry, Multidisciplinary

Recent advances in the chemistry and applications of N-heterocyclic carbenes

Peter Bellotti et al.

Summary: N-Heterocyclic carbenes have attracted significant interest due to their versatility, modularity and strong coordinating properties, leading to a rapid increase in utilization across various fields in the past decade. Future directions and recent developments in the field are also highlighted in this review.

NATURE REVIEWS CHEMISTRY (2021)

Review Chemistry, Multidisciplinary

Charge frustration in ligand design and functional group transfer

Dominik Munz et al.

Summary: This review discusses the importance of molecules with different resonance structures in various applications of chemistry, as well as the role of ambidentate/ambiphilic or cooperative ligands in coordination chemistry. By analyzing the historical development of organic zwitterions and various ligands and their metal complexes, new principles for ligand design are proposed, with potential future research directions highlighted.

NATURE REVIEWS CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

A quantitative metric for organic radical stability and persistence using thermodynamic and kinetic features

Shree S. Sowndarya et al.

Summary: The study shows that the long-term stability of organic radicals requires both thermodynamic and kinetic stability, and the molecular descriptors obtained through quantum chemical calculations can help predict the location of long-lived radicals. The radical stability score is an effective metric for evaluating stable radicals, outperforming thermodynamic scales based on bond dissociation enthalpies.

CHEMICAL SCIENCE (2021)

Review Chemistry, Multidisciplinary

Advances in chemistry of N-heterocyclic carbene boryl radicals

Tsuyoshi Taniguchi

Summary: Boron-centred radicals ligated by N-heterocyclic carbenes (NHCs) have shown potential in main group chemistry and synthetic chemistry due to their high stability and diverse applications; recent advances in the synthesis and reactions of NHC-boryl radicals have contributed significantly to radical chemistry, organoboron chemistry, and polymer science.

CHEMICAL SOCIETY REVIEWS (2021)

Article Chemistry, Physical

Mesoionic carbene-Breslow intermediates as super electron donors: Application to the metal-free arylacylation of alkenes

Wei Liu et al.

Summary: The newly discovered triazolylidenes mesoionic carbene have strong reducing ability, allowing them to undergo single-electron transfer with iodoarenes and efficiently catalyze arylacylation reactions on alkenes.

CHEM CATALYSIS (2021)

Review Chemistry, Multidisciplinary

Unconventional singlet fission materials

Tobias Ullrich et al.

Summary: Singlet fission is a photophysical downconversion pathway that transforms a singlet excitation into two triplet excited states, offering potential applications in solar energy conversion devices and other areas. While the mechanistic understanding of SF has evolved rapidly, the limited number of suitable SF-chromophores poses a challenge, necessitating the search for new SF materials.

CHEMICAL SOCIETY REVIEWS (2021)

Article Chemistry, Multidisciplinary

The transformations of a methylene-bridged bis-triazolium salt: a mesoionic carbene based metallocage and analogues of TCNE and NacNac

Jessica Stubbe et al.

Summary: The study reported the synthesis of a new methylene-bridged bis-triazolium salt as a precursor, which was used to prepare a novel carbene-silver(i) complex through metalation. The research also investigated the structural changes and chemical transformations that occurred during the process.

CHEMICAL SCIENCE (2021)

Article Chemistry, Multidisciplinary

Tethered CAAC-CAAC dimers: oxidation to persistent radical cations and bridging-unit dependent reactivity/stability of the dications

Mithilesh Kumar Nayak et al.

Summary: In this study, tethered cyclic(alkyl)(amino)carbene (CAAC) dimers were reported, in which two CAAC motifs are connected by an ethylene-, trans-1,2-cyclohexylene- and propylene-spacer through their N-centres. The 1-electron oxidized radical cations are isolable, and the bridging unit significantly affects the chemical reactivity in and with the 2-electron oxidized products.

CHEMICAL COMMUNICATIONS (2021)

Review Chemistry, Multidisciplinary

The Persistent Radical Effect in Organic Synthesis

Dirk Leifert et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Singlet Fission in Carbene-Derived Diradicaloids

Tobias Ullrich et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Inorganic & Nuclear

Carbodicarbene Ligand Redox Noninnocence in Highly Oxidized Chromium and Cobalt Complexes

Siu-Chung Chan et al.

INORGANIC CHEMISTRY (2020)

Article Chemistry, Multidisciplinary

Air-Stable Oxyallyl Patterns and a Switchable N-Heterocyclic Carbene

Eder Tomas-Mendivil et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Review Chemistry, Multidisciplinary

Air-Stable Organic Radicals: New-Generation Materials for Flexible Electronics?

Lei Ji et al.

ADVANCED MATERIALS (2020)

Article Chemistry, Multidisciplinary

Absolute Templating of M(111) Cluster Surrogates by Galvanic Exchange

Jesse L. Peltier et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Chemistry, Physical

Controlling Mobius-Type Helicity and the Excited-State Properties of Cumulenes with Carbenes

Piermaria Pinter et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2020)

Article Chemistry, Multidisciplinary

Aromaticity and sterics control whether a cationic olefin radical is resistant to disproportionation

Julian Messelberger et al.

CHEMICAL SCIENCE (2020)

Review Chemistry, Multidisciplinary

Recent advances in N-heterocyclic carbene-based radical catalysis

Takuya Ishii et al.

CHEMICAL SCIENCE (2020)

Article Chemistry, Multidisciplinary

Tuning the stability of organic radicals: from covalent approaches to non-covalent approaches

Bohan Tang et al.

CHEMICAL SCIENCE (2020)

Review Chemistry, Multidisciplinary

Platforms for Stable Carbon-Centered Radicals

Kenichi Kato et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Physical

A generally applicable atomic-charge dependent London dispersion correction

Eike Caldeweyher et al.

JOURNAL OF CHEMICAL PHYSICS (2019)

Article Chemistry, Multidisciplinary

Organic Redox Systems Based on Pyridinium-Carbene Hybrids

Patrick W. Antoni et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Multidisciplinary

Solvent Effects on the Stability and Delocalization of Aryl Dicyanomethyl Radicals: The Captodative Effect Revisited

Joshua P. Peterson et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Organic

Stable Carbon-Centered Radicals Based on N-Heterocyclic Carbenes

Rajendra S. Ghadwal

SYNLETT (2019)

Review Chemistry, Organic

Boryl Radical Addition to Multiple Bonds in Organic Synthesis

Tsuyoshi Taniguchi

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2019)

Article Chemistry, Multidisciplinary

What Are the Radical Intermediates in Oxidative Carbene Organocatalysis?

Vianney Regnier et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Review Chemistry, Multidisciplinary

Stable cyclic (alkyl)(amino)carbene (cAAC) radicals with main group substituents

Subrata Kundu et al.

CHEMICAL SCIENCE (2019)

Article Chemistry, Multidisciplinary

Software update: the ORCA program system, version 4.0

Frank Neese

WILEY INTERDISCIPLINARY REVIEWS-COMPUTATIONAL MOLECULAR SCIENCE (2018)

Article Chemistry, Multidisciplinary

Crystalline Radicals Derived from Classical N-Heterocyclic Carbenes

Dennis Rottschaefer et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Chemistry, Multidisciplinary

An air-stable N-heterocyclic carbene iminoxyl borate radical zwitterion

Youngsuk Kim et al.

CHEMICAL COMMUNICATIONS (2018)

Review Chemistry, Multidisciplinary

NHCs in Main Group Chemistry

Vitaly Nesterov et al.

CHEMICAL REVIEWS (2018)

Review Chemistry, Multidisciplinary

Electronic Properties of N-Heterocyclic Carbenes and Their Experimental Determination

Han Vinh Huynh

CHEMICAL REVIEWS (2018)

Article Chemistry, Multidisciplinary

Modular Approach to Kekule Diradicaloids Derived from Cyclic (Alkyl)(amino)carbenes

Max M. Hansmann et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Chemistry, Inorganic & Nuclear

Pushing Electrons-Which Carbene Ligand for Which Application?

Dominik Munz

ORGANOMETALLICS (2018)

Review Chemistry, Multidisciplinary

Stable Organic Radicals Derived from N-Heterocyclic Carbenes

Youngsuk Kim et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

Editorial Material Chemistry, Multidisciplinary

Introduction: Carbene Chemistry

F. Ekkehardt Hahn

CHEMICAL REVIEWS (2018)

Article Chemistry, Multidisciplinary

Pyrylenes: A New Class of Tunable, Redox-Switchable, Photoexcitable Pyrylium-Carbene Hybrids with Three Stable Redox-States

Patrick W. Antoni et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Chemistry, Multidisciplinary

Oxime Ether Radical Cations Stabilized by N-Heterocyclic Carbenes

Youngsuk Kim et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Chemistry, Multidisciplinary

N-Heterocyclic Carbene Stabilized Boryl Radicals

Miguel F. Silva Valverde et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Review Chemistry, Inorganic & Nuclear

What Wanzlick Did Not Dare To Dream: Cyclic (Alkyl)(amino) carbenes (cAACs) as New Key Players in Transition-Metal Chemistry

Ursula S. D. Paul et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2017)

Article Chemistry, Multidisciplinary

Triazenyl Radicals Stabilized by &ITN&IT-Heterocyclic Carbenes

Jisu Back et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Review Chemistry, Multidisciplinary

Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments

Mohand Melaimi et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Review Chemistry, Multidisciplinary

Catalysis of Radical Reactions: A Radical Chemistry Perspective

Armido Studer et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Review Chemistry, Multidisciplinary

N,N'-Diamidocarbenes: Isolable Divalent Carbons with Bona Fide Carbene Reactivity

Jonathan P. Moerdyk et al.

ACCOUNTS OF CHEMICAL RESEARCH (2016)

Review Chemistry, Multidisciplinary

Cyclic Alkyl(amino) Carbene Stabilized Complexes with Low Coordinate Metals of Enduring Nature

Sudipta Roy et al.

ACCOUNTS OF CHEMICAL RESEARCH (2016)

Article Chemistry, Multidisciplinary

NHC-CAAC Heterodimers with Three Stable Oxidation States

Dominik Munz et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Article Chemistry, Multidisciplinary

Synthesis of Hemilabile Cyclic (Alkyl)(amino)carbenes (CAACs) and Applications in Organometallic Chemistry

Jiaxiang Chu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Article Chemistry, Multidisciplinary

Neutral zero-valent s-block complexes with strong multiple bonding

Merle Arrowsmith et al.

NATURE CHEMISTRY (2016)

Article Chemistry, Multidisciplinary

Estimating π Binding Energy of N-Heterocyclic Carbenes: The Role of Polarization

Elixabete Rezabal et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2015)

Article Chemistry, Multidisciplinary

N-Heterocyclic Carbene Nitric Oxide Radicals

Junbeom Park et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Article Chemistry, Multidisciplinary

N-Heterocyclic Carbene-Catalyzed Radical Reactions for Highly Enantioselective β-Hydroxylation of Enals

Yuexia Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Article Chemistry, Multidisciplinary

Air-Persistent Monomeric (Amino)(carboxy) Radicals Derived from Cyclic (Alkyl)(Amino) Carbenes

Janell K. Mahoney et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Article Chemistry, Inorganic & Nuclear

Bonding Analysis of TM(cAAC)2 (TM = Cu, Ag, and Au) and the Importance of Reference State

Clark R. Landis et al.

ORGANOMETALLICS (2015)

Article Chemistry, Multidisciplinary

NHC-catalysed benzoin condensation - is it all down to the Breslow intermediate?

Julia Rehbein et al.

CHEMICAL SCIENCE (2015)

Review Chemistry, Multidisciplinary

Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise

Michele Soleilhavoup et al.

ACCOUNTS OF CHEMICAL RESEARCH (2015)

Article Chemistry, Multidisciplinary

Isolation of a Neutral Boron-Containing Radical Stabilized by a Cyclic (Alkyl)(Amino) Carbene

Philipp Bissinger et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Article Chemistry, Multidisciplinary

An efficient synthetic route to stable bis(carbene)borylenes [(L-1)(L-2)BH]

David A. Ruiz et al.

CHEMICAL COMMUNICATIONS (2014)

Article Chemistry, Physical

Physical Meaning of Virtual Kohn-Sham Orbitals and Orbital Energies: An Ideal Basis for the Description of Molecular Excitations

R. van Meer et al.

JOURNAL OF CHEMICAL THEORY AND COMPUTATION (2014)

Article Chemistry, Multidisciplinary

An Air-Stable Oxyallyl Radical Cation

David Martin et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

Article Chemistry, Multidisciplinary

Tetrathiafulvalene: the advent of organic metals

Nazario Martin

CHEMICAL COMMUNICATIONS (2013)

Review Chemistry, Multidisciplinary

Quantifying and understanding the electronic properties of N-heterocyclic carbenes

David J. Nelson et al.

CHEMICAL SOCIETY REVIEWS (2013)

Article Chemistry, Physical

Natural triple excitations in local coupled cluster calculations with pair natural orbitals

Christoph Riplinger et al.

JOURNAL OF CHEMICAL PHYSICS (2013)

Article Chemistry, Physical

An efficient and near linear scaling pair natural orbital based local coupled cluster method

Christoph Riplinger et al.

JOURNAL OF CHEMICAL PHYSICS (2013)

Article Chemistry, Organic

Electronic Structural Trends in Divalent Carbon Compounds

Han Vinh Huynh et al.

JOURNAL OF ORGANIC CHEMISTRY (2013)

Article Chemistry, Multidisciplinary

Bottleable (Amino)(Carboxy) Radicals Derived from Cyclic (Alkyl)(Amino) Carbenes

Janell K. Mahoney et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Article Chemistry, Organic

Stable Carbenes: From 'Laboratory Curiosities' to Catalysis Mainstays

Tomislav Rovis et al.

SYNLETT (2013)

Review Chemistry, Multidisciplinary

Carbene-stabilized main group radicals and radical ions

Caleb D. Martin et al.

CHEMICAL SCIENCE (2013)

Article Chemistry, Multidisciplinary

Umpolung by N-Heterocyclic Carbenes: Generation and Reactivity of the Elusive 2,2-Diamino Enols (Breslow Intermediates)

Albrecht Berkessel et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

Article Chemistry, Multidisciplinary

Do Carbenes Have a Hidden Carbon(0) Character? Revisiting the Electronic Structure of 2,2'-Bipyridyl Carbene

Ankur Kanti Guha et al.

CHEMISTRY-A EUROPEAN JOURNAL (2012)

Article Chemistry, Inorganic & Nuclear

Reactivity of an Oxalamid-Based N-Heterocyclic Carbene

Markus Braun et al.

ORGANOMETALLICS (2012)

Article Chemistry, Multidisciplinary

The ORCA program system

Frank Neese

WILEY INTERDISCIPLINARY REVIEWS-COMPUTATIONAL MOLECULAR SCIENCE (2012)

Article Chemistry, Inorganic & Nuclear

Redox Noninnocence of Carbene Ligands: Carbene Radicals in (Catalytic) C-C Bond Formation

Wojciech I. Dzik et al.

INORGANIC CHEMISTRY (2011)

Article Chemistry, Physical

An overlap fitted chain of spheres exchange method

Robert Izsak et al.

JOURNAL OF CHEMICAL PHYSICS (2011)

Article Chemistry, Physical

Weak Molecular Interactions Studied with Parallel Implementations of the Local Pair Natural Orbital Coupled Pair and Coupled Cluster Methods

Dimitrios G. Liakos et al.

JOURNAL OF CHEMICAL THEORY AND COMPUTATION (2011)

Article Chemistry, Multidisciplinary

Effect of the Damping Function in Dispersion Corrected Density Functional Theory

Stefan Grimme et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2011)

Article Chemistry, Organic

To Bend or Not to Bend! The Dilemma of Allenes

Dhilon S. Patel et al.

JOURNAL OF ORGANIC CHEMISTRY (2011)

Article Chemistry, Multidisciplinary

Electron Paramagnetic Resonance and Computational Studies of Radicals Derived from Boron-Substituted N-Heterocyclic Carbene Boranes

John C. Walton et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

Article Chemistry, Multidisciplinary

N-Heterocyclic carbenes versus transition metals for stabilizing phosphinyl radicals

Olivier Back et al.

CHEMICAL SCIENCE (2011)

Review Chemistry, Multidisciplinary

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

Mohand Melaimi et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

Article Chemistry, Multidisciplinary

Crystalline 1H-1,2,3-Triazol-5-ylidenes: New Stable Mesoionic Carbenes (MICs)

Gregorio Guisado-Barrios et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

Article Chemistry, Multidisciplinary

Carbodicarbenes and Related Divalent Carbon(0) Compounds

Susanne Klein et al.

CHEMISTRY-A EUROPEAN JOURNAL (2010)

Article Chemistry, Multidisciplinary

Borane-Lewis Base Complexes as Homolytic Hydrogen Atom Donors

Johnny Hioe et al.

CHEMISTRY-A EUROPEAN JOURNAL (2010)

Article Chemistry, Multidisciplinary

EPR Studies of the Generation, Structure, and Reactivity of N-Heterocyclic Carbene Borane Radicals

John C. Walton et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

Article Chemistry, Physical

A comparison of methods for measuring relative radical stabilities of carbon-centred radicals

Michelle L. Coote et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2010)

Article Chemistry, Organic

Radical stability and its role in synthesis and catalysis

Johnny Hioe et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2010)

Editorial Material Multidisciplinary Sciences

Radical Ligands Confer Nobility on Base-Metal Catalysts

Paul J. Chirik et al.

SCIENCE (2010)

Review Chemistry, Multidisciplinary

Accurate Theoretical Chemistry with Coupled Pair Models

Frank Neese et al.

ACCOUNTS OF CHEMICAL RESEARCH (2009)

Article Chemistry, Multidisciplinary

Synthesis and Ligand Properties of a Persistent, All-Carbon Four-Membered-Ring Allene

Mohand Melaimi et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)

Editorial Material Chemistry, Multidisciplinary

Carbenes Introduction

Anthony J. Arduengo et al.

CHEMICAL REVIEWS (2009)

Article Chemistry, Multidisciplinary

N-Heterocyclic Carbene Boryl Radicals: A New Class of Boron-Centered Radical

Shau-Hua Ueng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

Article Chemistry, Multidisciplinary

An N,N′-Diamidocarbene: Studies in C-H Insertion, Reversible Carbonylation, and Transition-Metal Coordination Chemistry

Todd W. Hudnall et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

Article Chemistry, Multidisciplinary

Coordination chemistry at carbon

Manuel Alcarazo et al.

NATURE CHEMISTRY (2009)

Article Chemistry, Inorganic & Nuclear

A Borenium Cation Stabilized by an N-Heterocyclic Carbene Ligand

Takeshi Matsumoto et al.

ORGANOMETALLICS (2009)

Article Chemistry, Multidisciplinary

Synthesis and ligand properties of stable five-membered-ring allenes containing only second-row elements

Vincent Lavallo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

Article Chemistry, Multidisciplinary

Coordination chemistry of ene-1,1-diamines and a prototype Carbodicarbene

Alois Fuerstner et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

Article Chemistry, Multidisciplinary

Synthesis of an extremely bent acyclic allene (A Carbodicarbene): A strong donor ligand

C. Adam Dyker et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

Article Chemistry, Multidisciplinary

Biomimetic Carbene-Catalyzed Oxidations of Aldehydes Using TEMPO

Joyram Guin et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

Article Chemistry, Multidisciplinary

Divalent carbon(0) chemistry, part 1: Parent compounds

Ralf Tonner et al.

CHEMISTRY-A EUROPEAN JOURNAL (2008)

Article Chemistry, Multidisciplinary

Divalent carbon(0) chemistry, part 2: Protonation and complexes with main group and transition metal lewis acids

Ralf Tonner et al.

CHEMISTRY-A EUROPEAN JOURNAL (2008)

Article Chemistry, Physical

First and second proton affinities of carbon bases

Ralf Tonner et al.

CHEMPHYSCHEM (2008)

Article Chemistry, Multidisciplinary

Hartree-Fock exchange fitting basis sets for H to Rn

Florian Weigend

JOURNAL OF COMPUTATIONAL CHEMISTRY (2008)

Letter Chemistry, Multidisciplinary

Replique: A new concept for bonding in carbodiphosphoranes?

Hubert Schmidbaur

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2007)

Article Chemistry, Multidisciplinary

Strong two-photon absorption of singlet diradical hydrocarbons

Kenji Kamada et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2007)

Article Chemistry, Inorganic & Nuclear

Deprotonation of N-heterocyclic carbenes to afford heterobimetallic organolanthanide complexes

PL Arnold et al.

ORGANOMETALLICS (2006)

Article Chemistry, Multidisciplinary

Carbodiphosphoranes: The chemistry of divalent Carbon(0)

Ralf Tonner et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2006)

Article Chemistry, Multidisciplinary

Isolation of cyclopropenylidene-lithium adducts: The Weiss-Yoshida reagent

Vincent Lavallo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2006)

Article Chemistry, Multidisciplinary

Synthesis, reactivity, and ligand properties of a stable alkyl carbene

V Lavallo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2004)

Review Chemistry, Multidisciplinary

Conceptual density functional theory

P Geerlings et al.

CHEMICAL REVIEWS (2003)