Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 364, Issue 14, Pages 2352-2357Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202200419
Keywords
amination; carbazole; C-H activation; Pd-catalyzed; perester; water
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An intramolecular C-H amination for the synthesis of carbazoles with a Pd(II)/TBPB system has been developed. This method forms carbazole products in good to excellent yields. Notably, the use of water as solvent in this catalytic process is also effective.
An intramolecular C-H amination for the synthesis of carbazoles with a Pd(II)/TBPB system has been developed. This catalytic amination process forms the carbazole products in good to excellent yields. It is noteworthy that this method implied the advantages of the catalytic mode involving perester with transition metal catalyst in the activation of inert C-H bonds. In addition, the transformation performs well using water as solvent.
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