4.8 Article

Visible-Light-Curable Acrylic Resins toward UV-Light-Blocking Adhesives for Foldable Displays

Journal

ADVANCED MATERIALS
Volume 35, Issue 43, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.202204776

Keywords

foldable displays; oxygen-tolerance; photocatalysts; UV-blocking adhesive; visible-light curing

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Current technological advances require the development of advanced adhesives with UV-blocking abilities for use in foldable smartphones and other flexible displays. A new acrylic resin that can be cured using visible light without oxygen removal is presented, along with a novel photocatalyst and additives that facilitate rapid curing under visible light, resulting in UV-blocking adhesive films with high transparency.
Current technological advances in the organic light-emitting diode panel design of foldable smartphones demand advanced adhesives with UV-blocking abilities, beyond their conventional roles of bonding objects and relieving deformation stress. However, optically clear adhesives (OCAs) with UV-blocking ability cannot be prepared using conventional UV-curing methods relying on a photoinitiator. Herein, a new acrylic resin that can be efficiently cured using visible light without oxygen removal is presented, which may be used to develop UV-blocking OCAs for use in current flexible displays. A novel photocatalyst and a specific combination of additives facilitate sufficiently rapid curing under visible light in the presence of UV-absorbers. Only a very small amount of the highly active photocatalyst is required to prepare UV-blocking OCA films with very high transparency in the visible region. Using this system, a UV-blocking OCA that nearly meets the specifications of an OCA used in commercialized foldable smartphones is realized. This technology can also be utilized in other applications that require highly efficient visible light curing, such as optically clear resins, dental resins, and 3D/4D-printable materials.

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