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Catalytic Effects of Electrodes and Electrolytes in Metal-Sulfur Batteries: Progress and Prospective

ADVANCED MATERIALS (2022)

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Summary: In this study, indium tin oxide nanoparticles decorated activated carbon cloth were used as an electrocatalytic substrate to reduce polysulfide-shuttling in room-temperature sodium-sulfur batteries, leading to improved performance and cycling stability. Additionally, subzero-temperature sodium-sulfur battery operation was successfully demonstrated for the first time.

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Nano high-entropy alloy with strong affinity driving fast polysulfide conversion towards stable lithium sulfur batteries

Hongfei Xu et al.

Summary: Experimental results show that nano-HEA plays a critical role in the multi-electron and multiphase conversions of lithium polysulfides in lithium-sulfur batteries, significantly enhancing the activity of LiPSs, reducing concentration polarization, and suppressing activation polarization, contributing to higher reaction rates.

ENERGY STORAGE MATERIALS (2021)

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Article Chemistry, Physical

Reversible function switching of Ag catalyst in Mg/S battery with chloride-containing electrolyte

Yan Xu et al.

Summary: By using Ag catalyst and Cl- containing electrolyte in Mg/S cells, the specific capacity and cycling life can be greatly improved. Experimental results reveal a reversible function switching mechanism of Ag catalyst in charge/discharge cycling.

ENERGY STORAGE MATERIALS (2021)

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Review Chemistry, Physical

Polyoxometalate-Single Atom Catalysts (POM-SACs) in Energy Research and Catalysis

Rongji Liu et al.

Summary: Single atom catalysts (SACs) anchored on molecular metal oxides (POMs) offer unrivalled possibilities for understanding complex systems on the atomic level. Research in this area focuses on energy conversion and storage technologies, but current limitations and potential future developments need to be addressed for further advancement in the field.

ADVANCED ENERGY MATERIALS (2021)

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Review Chemistry, Physical

Defect Engineering for Expediting Li-S Chemistry: Strategies, Mechanisms, and Perspectives

Zixiong Shi et al.

Summary: Lithium-sulfur (Li-S) batteries have attracted growing scientific and industrial interest due to their high energy density and low materials costs, with recent research focusing on improving the reaction kinetics of sulfur species through defect engineering. While defect engineering has emerged as a key strategy to enhance polysulfide modulation, there is still a lack of comprehensive overview in this field.

ADVANCED ENERGY MATERIALS (2021)

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Article Materials Science, Composites

Hierarchical porous carbon nanofibers with lithiophilic metal oxide crystalline grains for long-life Li metal anodes

Chengcheng Zhao et al.

Summary: A composite of ZnO/carbon nanofibers has been designed as a lithiophilic host to improve the uniformity of Li plating/stripping, reduce internal stress, and provide abundant electrolyte/Li interfaces, thereby enhancing cycling stability and battery performance.

COMPOSITES COMMUNICATIONS (2021)

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Article Chemistry, Physical

Hollow SiOx/C Microspheres with Semigraphitic Carbon Coating as the Lithium Host for Dendrite-Free Lithium Metal Anodes

Chang Yu et al.

Summary: A SiOx/C@SGC lithium host material with excellent Coulombic efficiency and stability has been successfully prepared through the design of a three-dimensional host. The synergistic effect of the lithiophilic inner shell and highly conductive SGC coating layer effectively controls the growth of lithium.

ACS APPLIED ENERGY MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Manipulating the Electronic Structure of Nickel via Alloying with Iron: Toward High-Kinetics Sulfur Cathode for Na-S Batteries

Lifeng Wang et al.

Summary: Through density functional theory calculations, the study reveals that alloying Fe into Ni can optimize the electronic structure and enhance the efficiency of polysulfide conversion. The designed sulfur host FeNi3@HC shows excellent cycling stability and rate performance, showcasing an effective electrocatalyst design strategy for RT Na-S batteries.

ACS NANO (2021)

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Article Chemistry, Multidisciplinary

Mo2N-W2N Heterostructures Embedded in Spherical Carbon Superstructure as Highly Efficient Polysulfide Electrocatalysts for Stable Room-Temperature Na-S Batteries

Shipeng Zhang et al.

Summary: In this study, a Mo2N-W2N heterostructure embedded in a spherical carbon superstructure was designed to promote NaPS redox reactions and suppress the polysulfide shuttle effect, achieving high-performance Na-S batteries. The obtained battery showed high reversible capacity, superior long-term stability, and excellent rate capability.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Mo2C/C Hierarchical Double-Shelled Hollow Spheres as Sulfur Host for Advanced Li-S Batteries

Wanli Li et al.

Summary: The Mo2C/C HDS-HSs structure effectively addresses the challenges of the sulfur cathode in Li-S batteries, improving battery performance and cycling stability.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Electrochemistry

Metal iodides (LiI, MgI2, AlI3, TiI4, and SnI4) potentiality as electrolyte additives for Li-S batteries

Sollee Kim et al.

Summary: Investigated the effects of various metal iodides as additives in the electrolyte used in Li-S batteries, finding that LiI and MgI2 additives help form a stable solid electrolyte interphase (SEI) layer on the Li metal and suppress the polysulfide shuttle reaction.

ELECTROCHIMICA ACTA (2021)

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Article Chemistry, Physical

Sodiophilic Au/reduced-graphene-oxide for dendrite free sodium metal anode

Hui Wang et al.

Summary: In this work, a nanocomposite of gold nanoparticles supported by reduced graphene oxide is designed as a host for a sodium metal anode, exhibiting excellent electrochemical performance with dendrite-free morphology. The unique sodiophilic surface enabled by the gold nanoparticles guides uniform sodium deposition, inhibiting dendrite formation and proving to be a promising host for sodium metal anodes.

JOURNAL OF POWER SOURCES (2021)

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Article Chemistry, Multidisciplinary

Tunable Nitrogen-Doping of Sulfur Host Nanostructures for Stable and Shuttle-Free Room-Temperature Sodium-Sulfur Batteries

Alex Yong Sheng Eng et al.

Summary: This study investigates the impact of nitrogen-doping on the performance of sodium-sulfur batteries, finding that highly doped nitrogen-doped nanocarbon host, despite its lower conductivity, exhibits better Coulombic efficiency and stability, retaining a high capacity after 800 cycles. This suggests that nitrogen-doping should be prioritized in designing shuttle-free, long-life sodium-sulfur batteries.

NANO LETTERS (2021)

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Article Chemistry, Physical

Achieving Efficient Magnesium-Sulfur Battery Chemistry via Polysulfide Mediation

Qingli Zou et al.

Summary: Magnesium-sulfur batteries offer higher theoretical volumetric energy density and lower cost compared to lithium-sulfur batteries, but suffer from poor cycle life and low energy efficiency. By increasing polysulfide solubility with high-donor-number solvents like dimethyl sulfoxide (DMSO), the discharge capacity and sulfur overpotential can be improved, leading to higher performance and reversible cycling.

ADVANCED ENERGY MATERIALS (2021)

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Article Chemistry, Physical

Morphology, chemistry, performance trident: Insights from hollow, mesoporous carbon nanofibers for dendrite-free sodium metal batteries

Nauman Mubarak et al.

Summary: The study developed a HpCNF host for sodium metal batteries, demonstrating excellent sodium deposition performance through a combination of in situ and cryogenic microscopy examinations, and theoretical simulations. In experiments, Na@HpCNF anodes exhibited high cycling stability and Coulombic efficiency, while full cells paired with them also showed outstanding specific capacities.

NANO ENERGY (2021)

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Article Chemistry, Physical

Single Cobalt Atoms Decorated N-doped Carbon Polyhedron Enabled Dendrite-Free Sodium Metal Anode

Yijuan Li et al.

Summary: Controlling the growth of sodium dendrites during sodium deposition and stripping processes is a significant challenge for high-performance sodium metal batteries (SMBs). By embedding single cobalt atoms into nitrogen-doped carbon electrodes, stable Na-philic sites are provided to guide uniform sodium deposition and prevent the growth of sodium dendrites. This work offers an effective solution to inhibit sodium dendrite growth and control sodium nucleation behavior at the atomic level, leading to the fabrication of high-safety and long-cycling SMBs.

SMALL METHODS (2021)

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Article Chemistry, Physical

Size-Dependent Cobalt Catalyst for Lithium Sulfur Batteries: From Single Atoms to Nanoclusters and Nanoparticles

Xing Zhou et al.

Summary: This study systematically investigates the size-dependent catalytic activity of Co catalysts in polysulfides conversion, demonstrating that single atomic Co exhibits superior charge transfer kinetics. By lowering the energy barrier for Li2S nucleation/dissolution, single atomic Co shows promising potential for high specific capacity in long-term cycling. The findings highlight the importance of size-dependent catalytic activity in enhancing the overall performance of Li-S batteries.

SMALL METHODS (2021)

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Article Chemistry, Physical

Multifunctional SnSe-C composite modified 3D scaffolds to regulate lithium nucleation and fast transport for dendrite-free lithium metal anodes

Xiaojie Shen et al.

Summary: The multifunctional SnSe-C composite modified 3D scaffolds successfully regulate lithium nucleation and transport, leading to dendrite-free lithium deposition and improved performance of the Li/SnSe-C anode.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Review Chemistry, Physical

Carbon materials for stable Li metal anodes: Challenges, solutions, and outlook

Qiongqiong Lu et al.

Summary: Carbon materials have shown excellent effectiveness in stabilizing lithium metal anodes by accommodating and guiding lithium deposition, as well as stabilizing the interface, addressing the fundamental challenges of lithium metal anodes and benefiting practical applications.

CARBON ENERGY (2021)

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Article Chemistry, Physical

A novel one-step reaction sodium-sulfur battery with high areal sulfur loading on hierarchical porous carbon fiber

Qiubo Guo et al.

Summary: Room temperature sodium-sulfur batteries utilizing activated porous carbon fibers with small sulfur molecules show promising results in achieving reversible single-step reaction and high sulfur utilization, providing a new strategy for the development of high capacity energy storage systems.

CARBON ENERGY (2021)

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Review Chemistry, Multidisciplinary

Recent advanced skeletons in sodium metal anodes

Chenxiao Chu et al.

Summary: Sodium metal anodes have high theoretical capacity and low redox potential, but face challenges such as dendrite growth. Using skeleton materials is an effective strategy to reduce local current density, inhibit dendrite growth, and alleviate volume expansion in sodium metal anodes.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Review Chemistry, Multidisciplinary

Materials engineering for adsorption and catalysis in room-temperature Na-S batteries

Xiang Long Huang et al.

Summary: Room-temperature sodium-sulfur (RT Na-S) batteries offer a competitive electrochemical energy storage system with abundant natural resources and low cost, but face challenges such as the shuttle effect and sluggish reaction kinetics. Research into adsorption and catalysis strategies for RT Na-S chemistry is crucial, with various adsorption strategies and electrocatalysis engineering playing significant roles in addressing these challenges.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Article Chemistry, Physical

Sodiated NaxSnSb nanoparticles embedded in N-doped graphene sponges direct uniform Na nucleation and smooth plating for high efficiency Na metal batteries

Zhida Wang et al.

Summary: The team reported a composite sponge for modulating sodium anodes, which significantly improves stability and fast charging capability. The sponge allows the sodium anode to cycle hundreds of times without being affected, maintaining high efficiency through guided growth and shielding.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Physical

Highly reversible aluminium-sulfur batteries obtained through effective sulfur confinement with hierarchical porous carbon†

Dian Zhang et al.

Summary: A nitrogen-doped hierarchical porous carbon material was developed to improve the electrochemical performance and stability of aluminum-sulfur batteries. By utilizing a low-cost electrolyte and a sulfur composite cathode, the battery showed significant improvements in cycling performance and capacity. This study sheds light on the design of composite cathodes for high-reversibility, high-capacity, and low-cost Al-S batteries.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Multidisciplinary

Sb nanosheet modified separator for Li-S batteries with excellent electrochemical performance

Linchao Zeng et al.

Summary: An air-stable antimony nanosheet modified separator has been prepared by coating exfoliated Sb nanosheets onto a pristine separator, leading to much improved electrochemical performance in Li-S batteries. The batteries using SbNs/separators exhibit high coulombic efficiency, capacity retention, and rate capability, attributed to the physical adsorption, chemical bonding, and good electronic conductivity of SbNs. The SbNs/separators show great potential for future high-performance Li-S batteries.

RSC ADVANCES (2021)

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Article Chemistry, Physical

Enabling high-performance room-temperature sodium/sulfur batteries with few-layer 2H-MoSe2 embellished nitrogen-doped hollow carbon spheres as polysulfide barriers

Chunwei Dong et al.

Summary: This study presents a functional separator to suppress the shuttle effect in Room-temperature sodium/sulfur batteries, demonstrating a promising path for high-performance RT-Na/S batteries.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Review Chemistry, Physical

Rationalizing Electrocatalysis of Li-S Chemistry by Mediator Design: Progress and Prospects

Yingze Song et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Efficient Ni2Co4P3 Nanowires Catalysts Enhance Ultrahigh-Loading Lithium-Sulfur Conversion in a Microreactor-Like Battery

Zihan Shen et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

MXene-Based Dendrite-Free Potassium Metal Batteries

Xiao Tang et al.

ADVANCED MATERIALS (2020)

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Article Engineering, Environmental

3D TiO2@nitrogen-doped carbon/Fe7S8 composite derived from polypyrrole-encapsulated alkalized MXene as anode material for high-performance lithium-ion batteries

Xinlu Zhang et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Chemistry, Multidisciplinary

Single Zinc Atoms Immobilized on MXene (Ti3C2Clx) Layers toward Dendrite-Free Lithium Metal Anodes

Jianan Gu et al.

ACS NANO (2020)

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Article Chemistry, Multidisciplinary

Ti3C2Tx MXene-Reduced Graphene Oxide Composite Electrodes for Stretchable Supercapacitors

Yihao Zhou et al.

ACS NANO (2020)

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Article Chemistry, Multidisciplinary

Built-In Catalysis in Confined Nanoreactors for High-Loading Li-S Batteries

Qingping Wu et al.

ACS NANO (2020)

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Article Chemistry, Multidisciplinary

Regulating Lithium Nucleation and Deposition via MOF-Derived Co@C-Modified Carbon Cloth for Stable Li Metal Anode

Ting Zhou et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Electromagnetic Shielding of Monolayer MXene Assemblies

Taeyeong Yun et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Dendrite-Free Potassium Metal Anodes in a Carbonate Electrolyte

Pengcheng Liu et al.

ADVANCED MATERIALS (2020)

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Article Engineering, Environmental

Rational construction of rGO/VO2 nanoflowers as sulfur multifunctional hosts for room temperature Na-S batteries

Wenyan Du et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Engineering, Environmental

3D catalytic MOF-based nanocomposite as separator coatings for high-performance Li-S battery

Chun-Lei Song et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Review Chemistry, Multidisciplinary

Biomass-Derived Carbons for Sodium-Ion Batteries and Sodium-Ion Capacitors

Jianhui Zhu et al.

CHEMSUSCHEM (2020)

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Article Chemistry, Multidisciplinary

Revealing Principles for Design of Lean-Electrolyte Lithium Metal Anode via In Situ Spectroscopy

Huan Li et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Multidisciplinary

Theoretical Calculation Guided Design of Single-Atom Catalysts toward Fast Kinetic and Long-Life Li-S Batteries

Guangmin Zhou et al.

NANO LETTERS (2020)

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Article Chemistry, Multidisciplinary

Layer-Spacing-Enlarged MoS2 Superstructural Nanotubes with Further Enhanced Catalysis and Immobilization for Li-S Batteries

Yuelei Pan et al.

ACS NANO (2020)

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Article Chemistry, Multidisciplinary

Electrocatalyzing S Cathodes via Multisulfiphilic Sites for Superior Room-Temperature Sodium-Sulfur Batteries

Hanwen Liu et al.

ACS NANO (2020)

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Article Chemistry, Applied

FeCo alloy catalysts promoting polysulfide conversion for advanced lithium?sulfur batteries

Hongyi Li et al.

JOURNAL OF ENERGY CHEMISTRY (2020)

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Article Chemistry, Physical

In-situ topochemical nitridation derivative MoO2-Mo2N binary nanobelts as multifunctional interlayer for fast-kinetic Li-Sulfur batteries

Jin-Lin Yang et al.

NANO ENERGY (2020)

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Article Engineering, Environmental

Fabrication of novel CuFe2O4/MXene hierarchical heterostructures for enhanced photocatalytic degradation of sulfonamides under visible light

Yang Cao et al.

JOURNAL OF HAZARDOUS MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Integration of Binary Active Sites: Co3V2O8 as Polysulfide Traps and Catalysts for Lithium-Sulfur Battery with Superior Cycling Stability

Linlin Zhang et al.

SMALL (2020)

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Review Chemistry, Physical

Recent Progress in High Donor Electrolytes for Lithium-Sulfur Batteries

Hyuksoo Shin et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Chemistry, Physical

Petaloid-shaped ZnO coated carbon felt as a controllable host to construct hierarchical Li composite anode

Xin-Yang Yue et al.

NANO ENERGY (2020)

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Article Chemistry, Multidisciplinary

Multiregion Janus-Featured Cobalt Phosphide-Cobalt Composite for Highly Reversible Room-Temperature Sodium-Sulfur Batteries

Zichao Yan et al.

ACS NANO (2020)

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Article Chemistry, Multidisciplinary

Nitrogen Doping Improves the Immobilization and Catalytic Effects of Co9S8in Li-S Batteries

Yuping Liu et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

General Synthesis of Single-Atom Catalysts for Hydrogen Evolution Reactions and Room-Temperature Na-S Batteries

Wei-Hong Lai et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Enhanced Catalytic Conversion of Polysulfides Using Bimetallic Co7Fe3 for High-Performance Lithium-Sulfur Batteries

Pan Zeng et al.

ACS NANO (2020)

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Article Chemistry, Multidisciplinary

A Progress Report on Metal-Sulfur Batteries

Xingwen Yu et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Lewis Acid-Base Interactions between Polysulfides and Boehmite Enables Stable Room-Temperature Sodium-Sulfur Batteries

Arnab Ghosh et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Rechargeable Aluminium-Sulfur Battery with Improved Electrochemical Performance by Cobalt-Containing Electrocatalyst

Yue Guo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Engineering, Environmental

High performance room temperature Na-S batteries based on FCNT modified Co3C-Co nanocubes

Guohui Qin et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Chemistry, Physical

Spectroscopic Insights into the Electrochemical Mechanism of Rechargeable Calcium/Sulfur Batteries

Antonio Scafuri et al.

CHEMISTRY OF MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Mesoporous Nitrogen-Doped Carbon Nanospheres as Sulfur Matrix and a Novel Chelate-Modified Separator for High-Performance Room-Temperature Na-S Batteries

Huan Li et al.

SMALL (2020)

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Article Chemistry, Multidisciplinary

A Combined Ordered Macro-Mesoporous Architecture Design and Surface Engineering Strategy for High-Performance Sulfur Immobilizer in Lithium-Sulfur Batteries

Guihua Liu et al.

SMALL (2020)

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Article Chemistry, Physical

Template method for fabricating Co and Ni nanoparticles/porous channels carbon for solid-state sodium-sulfur battery

Qianru Ma et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2020)

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Article Chemistry, Physical

Defect engineering on carbon black for accelerated Li-S chemistry

Wenlong Cai et al.

NANO RESEARCH (2020)

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Article Chemistry, Multidisciplinary

Rechargeable Calcium-Sulfur Batteries Enabled by an Efficient Borate-Based Electrolyte

Zhenyou Li et al.

SMALL (2020)

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Article Multidisciplinary Sciences

Metal chalcogenide hollow polar bipyramid prisms as efficient sulfur hosts for Na-S batteries

Muhammad Kashif Aslam et al.

NATURE COMMUNICATIONS (2020)

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Article Chemistry, Physical

Engineering the Conductive Network of Metal Oxide-Based Sulfur Cathode toward Efficient and Longevous Lithium-Sulfur Batteries

Jiayi Wang et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Chemistry, Physical

A fundamental look at electrocatalytic sulfur reduction reaction

Lele Peng et al.

NATURE CATALYSIS (2020)

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Article Chemistry, Physical

Encapsulating sodium deposition into carbon rhombic dodecahedron guided by sodiophilic sites for dendrite-free Na metal batteries

Yangyang Xie et al.

ENERGY STORAGE MATERIALS (2020)

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Article Chemistry, Physical

Free-standing, flexible and stable potassium–sulfur battery enabled by controllable porous carbon cloth

Xiaomin Yuan et al.

JOURNAL OF POWER SOURCES (2020)

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Article Chemistry, Multidisciplinary

Metal-Organic Framework-Derived Nitrogen-Doped Cobalt Nanocluster Inlaid Porous Carbon as High-Efficiency Catalyst for Advanced Potassium-Sulfur Batteries

Xiaoli Ge et al.

ACS NANO (2020)

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Article Chemistry, Physical

Atomic level design of single iron atom embedded mesoporous hollow carbon spheres as multi-effect nanoreactors for advanced lithium-sulfur batteries

Qinjun Shao et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Chemistry, Inorganic & Nuclear

An MXene-based aerogel with cobalt nanoparticles as an efficient sulfur host for room-temperature Na-S batteries

Qiuju Yang et al.

INORGANIC CHEMISTRY FRONTIERS (2020)

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Review Chemistry, Multidisciplinary

Revitalising sodium-sulfur batteries for non-high-temperature operation: a crucial review

Yizhou Wang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

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Review Materials Science, Multidisciplinary

Two-dimensional MXenes for lithium-sulfur batteries

Chuanfang (John) Zhang et al.

INFOMAT (2020)

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Article Chemistry, Physical

In Situ Sulfurized Carbon-Confined Cobalt for Long-Life Mg/S Batteries

Ju Sun et al.

ACS APPLIED ENERGY MATERIALS (2020)

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Article Electrochemistry

Optimizing Calcium Electrolytes by Solvent Manipulation for Calcium Batteries

Kevin Nielson et al.

BATTERIES & SUPERCAPS (2020)

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Review Chemistry, Physical

Challenges and Key Parameters of Lithium-Sulfur Batteries on Pouch Cell Level

Susanne Doerfler et al.

JOULE (2020)

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Article Chemistry, Physical

Solid Additives for Improving the Performance of Sulfur Cathodes in Lithium-Sulfur Batteries-Adsorbents, Mediators, and Catalysts

Hualin Ye et al.

SMALL METHODS (2020)

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Article Chemistry, Physical

Dendrite-free lithium deposition by coating a lithiophilic heterogeneous metal layer on lithium metal anode

Feihu Guo et al.

ENERGY STORAGE MATERIALS (2020)

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Article Materials Science, Ceramics

Functionalized titanium nitride-based MXenes as promising host materials for lithium-sulfur batteries: A first principles study

He Lin et al.

CERAMICS INTERNATIONAL (2019)

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Review Chemistry, Physical

The latest advances in the critical factors (positive electrode, electrolytes, separators) for sodium-sulfur battery

Tiexin Li et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2019)

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Article Chemistry, Multidisciplinary

Cobalt in Nitrogen-Doped Graphene as Single-Atom Catalyst for High-Sulfur Content Lithium-Sulfur Batteries

Zhenzhen Du et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Chemistry, Physical

Dramatically Enhanced Ambient Ammonia Electrosynthesis Performance by In-Operando Created Li-S Interactions on MoS2 Electrocatalyst

Yanyan Liu et al.

ADVANCED ENERGY MATERIALS (2019)

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Article Chemistry, Physical

Synergistic Engineering of Defects and Architecture in Binary Metal Chalcogenide toward Fast and Reliable Lithium-Sulfur Batteries

Dan Luo et al.

ADVANCED ENERGY MATERIALS (2019)

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Article Chemistry, Physical

Efficient synergism of electrocatalysis and physical confinement leading to durable high-power lithium-sulfur batteries

Lingyu Du et al.

NANO ENERGY (2019)

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Review Chemistry, Multidisciplinary

Sodium Metal Anodes: Emerging Solutions to Dendrite Growth

Byeongyong Lee et al.

CHEMICAL REVIEWS (2019)

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Article Chemistry, Multidisciplinary

In Situ X-ray Absorption Spectroscopic Investigation of the Capacity Degradation Mechanism in Mg/S Batteries

Yan Xu et al.

NANO LETTERS (2019)

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Article Chemistry, Physical

Modelling high-performing batteries with Mxenes: The case of S-functionalized two-dimensional nitride Mxene electrode

Vivekanand Shukla et al.

NANO ENERGY (2019)

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Article Chemistry, Physical

Ultradispersed WxC nanoparticles enable fast polysulfide interconversion for high-performance Li-S batteries

Yunling Wu et al.

NANO ENERGY (2019)

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Review Chemistry, Multidisciplinary

Polymer Electrolytes for Lithium-Based Batteries: Advances and Prospects

Dong Zhou et al.

CHEM (2019)

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Review Materials Science, Ceramics

A review on transition metal nitrides as electrode materials for supercapacitors

Yansong Zhou et al.

CERAMICS INTERNATIONAL (2019)

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Article Chemistry, Physical

Capillary Encapsulation of Metallic Potassium in Aligned Carbon Nanotubes for Use as Stable Potassium Metal Anodes

Lei Qin et al.

ADVANCED ENERGY MATERIALS (2019)

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Article Chemistry, Physical

Separator Modified by Cobalt-Embedded Carbon Nanosheets Enabling Chemisorption and Catalytic Effects of Polysulfides for High-Energy-Density Lithium-Sulfur Batteries

Zhibin Cheng et al.

ADVANCED ENERGY MATERIALS (2019)

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Article Chemistry, Physical

MXene based self-assembled cathode and antifouling separator for high-rate and dendrite-inhibited Li-S battery

Dong Guo et al.

NANO ENERGY (2019)

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Article Nanoscience & Nanotechnology

Single-Atom Iron as Lithiophilic Site To Minimize Lithium Nucleation Overpotential for Stable Lithium Metal Full Battery

Yawen Sun et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Chemistry, Multidisciplinary

Boosting Performance of Na-S Batteries Using Sulfur-Doped Ti3C2Tx MXene Nanosheets with a Strong Affinity to Sodium Polysulfides

Weizhai Bao et al.

ACS NANO (2019)

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Article Chemistry, Physical

Fluorinated Covalent Organic Polymers for High Performance Sulfur Cathodes in Lithium-Sulfur Batteries

Hyuksoo Shin et al.

CHEMISTRY OF MATERIALS (2019)

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Article Chemistry, Physical

A Coaxial-Interweaved Hybrid Lithium Metal Anode for Long-Lifespan Lithium Metal Batteries

Xiao-Ru Chen et al.

ADVANCED ENERGY MATERIALS (2019)

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Article Chemistry, Physical

Original growth mechanism for ultra-stable dendrite-free potassium metal electrode

Yuqian Li et al.

NANO ENERGY (2019)

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Article Chemistry, Physical

Reversible Calcium Plating and Stripping at Room Temperature Using a Borate Salt

Abhinandan Shyamsunder et al.

ACS ENERGY LETTERS (2019)

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Article Nanoscience & Nanotechnology

Seed-Free Selective Deposition of Lithium Metal into Tough Graphene Framework for Stable Lithium Metal Anode

Linhai Pan et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Chemistry, Multidisciplinary

Lithiophilic Three -Dimensional Porous Ti3C2Tx-rGO Membrane as a Stable Scaffold for Safe Alkali Metal (Li or Na) Anodes

Yongzheng Fang et al.

ACS NANO (2019)

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Review Chemistry, Physical

Transition metal carbide catalysts for biomass conversion: A review

Jifeng Pang et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2019)

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Article Electrochemistry

Effects of transition metal cation additives on the passivation of lithium metal anode in Li-S batteries

Wenduo Zeng et al.

ELECTROCHIMICA ACTA (2019)

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Article Chemistry, Multidisciplinary

Mega High Utilization of Sodium Metal Anodes Enabled by Single Zinc Atom Sites

Tingzhou Yang et al.

NANO LETTERS (2019)

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Review Chemistry, Physical

Harnessing the unique properties of 2D materials for advanced lithium-sulfur batteries

Bin Li et al.

NANOSCALE HORIZONS (2019)

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Article Chemistry, Physical

Tin sulfide modified separator as an efficient polysulfide trapper for stable cycling performance in Li-S batteries

Brindha Moorthy et al.

NANOSCALE HORIZONS (2019)

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Article Multidisciplinary Sciences

Nickel sulfide nanocrystals on nitrogen-doped porous carbon nanotubes with high-efficiency electrocatalysis for room-temperature sodium-sulfur batteries

Zichao Yan et al.

NATURE COMMUNICATIONS (2019)

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Carbonized-MOF as a Sulfur Host for Aluminum-Sulfur Batteries with Enhanced Capacity and Cycling Life

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Cobalt-Doped SnS2 with Dual Active Centers of Synergistic Absorption-Catalysis Effect for High-S Loading Li-S Batteries

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Doping of Carbon Materials for Metal-Free Electrocatalysis

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Nonlithium Metal-Sulfur Batteries: Steps Toward a Leap

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Lithiophilic Faceted Cu(100) Surfaces: High Utilization of Host Surface and Cavities for Lithium Metal Anodes

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Long-Life Room-Temperature Sodium-Sulfur Batteries by Virtue of Transition-Metal-Nanocluster-Sulfur Interactions

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Activating Inert Metallic Compounds for High-Rate Lithium -Sulfur Batteries Through In Situ Etching of Extrinsic Metal

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Stepwise Electrocatalysis as a Strategy against Polysulfide Shuttling in Li-S Batteries

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Metal-Sulfur Batteries: Overview and Research Methods

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ACS ENERGY LETTERS (2019)

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Hierarchical Co3O4 Nanofiber-Carbon Sheet Skeleton with Superior Na/Li-Philic Property Enabling Highly Stable Alkali Metal Batteries

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Stable Na Plating and Stripping Electrochemistry Promoted by In Situ Construction of an Alloy-Based Sodiophilic Interphase

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Chemisorption and electrocatalytic effect from CoxSny alloy for high performance lithium sulfur batteries

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Accelerating polysulfide redox conversion on bifunctional electrocatalytic electrode for stable Li-S batteries

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Electrospun nanostructures for conversion type cathode (S, Se) based lithium and sodium batteries

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A low-cost deep eutectic solvent electrolyte for rechargeable aluminum-sulfur battery

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Towards stable and efficient electrolytes for room-temperature rechargeable calcium batteries

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Plating and stripping calcium in an organic electrolyte

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Synergistic Effect of Molecular-Type Electrocatalysts with Ultrahigh Pore Volume Carbon Microspheres for Lithium-Sulfur Batteries

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Development and Challenges of Functional Electrolytes for High-Performance Lithium-Sulfur Batteries

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Honeycomb-Like Spherical Cathode Host Constructed from Hollow Metallic and Polar Co9S8 Tubules for Advanced Lithium-Sulfur Batteries

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High Rate Magnesium-Sulfur Battery with Improved Cyclability Based on Metal-Organic Framework Derivative Carbon Host

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An Aluminum-Sulfur Battery with a Fast Kinetic Response

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Anchoring effects of S-terminated Ti2C MXene for lithium-sulfur batteries: A first-principles study

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Sulfur nanocomposite as a positive electrode material for rechargeable potassium-sulfur batteries

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Long-life and high-areal-capacity lithium-sulfur batteries realized by a honeycomb-like N, P dual-doped carbon modified separator

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TiO2 nanowire array as a polar absorber for high-performance lithium-sulfur batteries

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Remedies of capacity fading in room-temperature sodium-sulfur batteries

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Low Cost Metal Carbide Nanocrystals as Binding and Electrocatalytic Sites for High Performance Li-S Batteries

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N-Doped Graphene Modified 3D Porous Cu Current Collector toward Microscale Homogeneous Li Deposition for Li Metal Anodes

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Regulating the polysulfide redox conversion by iron phosphide nanocrystals for high-rate and ultrastable lithium-sulfur battery

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Toward High-Safety Potassium-Sulfur Batteries Using a Potassium Polysulfide Catholyte and Metal-Free Anode

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Room-Temperature Aluminum-Sulfur Batteries with a Lithium-Ion-Mediated Ionic Liquid Electrolyte

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Enhanced Electrochemical Kinetics and Polysulfide Traps of Indium Nitride for Highly Stable Lithium-Sulfur Batteries

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Electrocatalysis in Lithium Sulfur Batteries under Lean Electrolyte Conditions

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A room-temperature sodium-sulfur battery with high capacity and stable cycling performance

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Atomic cobalt as an efficient electrocatalyst in sulfur cathodes for superior room-temperature sodium-sulfur batteries

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NATURE COMMUNICATIONS (2018)

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Recessed deposition of TiN into N-doped carbon as a cathode host for superior Li-S batteries performance

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Toward Highly Reversible Magnesium-Sulfur Batteries with Efficient and Practical Mg[B(hfip)(4)](2) Electrolyte

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Directional Flow-Aided Sonochemistry Yields Graphene with Tunable Defects to Provide Fundamental Insight on Sodium Metal Plating Behavior

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Nickel-Cobalt Double Hydroxide as a Multifunctional Mediator for Ultrahigh-Rate and Ultralong-Life Li-S Batteries

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Inhibiting Polysulfide Shuttling with a Graphene Composite Separator for Highly Robust Lithium-Sulfur Batteries

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Metal-based nanostructured materials for advanced lithium-sulfur batteries

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Stable Li metal anode with protected interface for high-performance Li metal batteries

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Honeycomb-like porous 3D nickel electrodeposition for stable Li and Na metal anodes

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On the road toward calcium-based batteries

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CURRENT OPINION IN ELECTROCHEMISTRY (2018)

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A Review of Advanced Energy Materials for Magnesium-Sulfur Batteries

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In operando observation of chemical and mechanical stability of Li and Na dendrites under quasi-zero electrochemical field

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A Bifunctional Perovskite Promoter for Polysulfide Regulation toward Stable Lithium-Sulfur Batteries

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Volumetric expansion of Lithium-Sulfur cell during operation Fundamental insight into applicable characteristics

Sylwia Walus et al.

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Carbon hollow nanobubbles on porous carbon nanofibers: An ideal host for high-performance sodium-sulfur batteries and hydrogen storage

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A reversible nonaqueous room-temperature potassium-sulfur chemistry for electrochemical energy storage

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Potassium Secondary Batteries

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Transition Metal Dichalcogenide Atomic Layers for Lithium Polysulfides Electrocatalysis

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Ultrathin Surface Coating Enables the Stable Sodium Metal Anode

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Carbon Composites for a High-Energy Lithium-Sulfur Battey with a Glyme-Based Electrolyte

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Twinborn TiO2-TiN heterostructures enabling smooth trapping-diffusion-conversion of polysulfides towards ultralong life lithium-sulfur batteries

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Electrocatalysis of polysulfide conversion by sulfur-deficient MoS2 nanoflakes for lithium-sulfur batteries

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Electrolyte design strategies and research progress for room-temperature sodium-ion batteries

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High-safety lithium-ion sulfur battery with sulfurized polyacrylonitrile cathode, prelithiated SiOx/C anode and carbonate-based electrolyte

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A Sugar-Derived Room-Temperature Sodium Sulfur Battery with Long Term Cycling Stability

Rachel Carter et al.

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Porous Al Current Collector for Dendrite-Free Na Metal Anodes

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Air-stable and freestanding lithium alloy/graphene foil as an alternative to lithium metal anodes

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Amorphous MoS3 as the sulfur-equivalent cathode material for room-temperature Li-S and Na-S batteries

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Catalytic oxidation of Li2S on the surface of metal sulfides for Li-S batteries

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A Delicately Designed Sulfide Graphdiyne Compatible Cathode for High-Performance Lithium/Magnesium-Sulfur Batteries

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SMALL (2017)

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Designing solid-liquid interphases for sodium batteries

Snehashis Choudhury et al.

NATURE COMMUNICATIONS (2017)

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Conductive porous vanadium nitride/graphene composite as chemical anchor of polysulfides for lithium-sulfur batteries

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Room-Temperature Sodium-Sulfur Batteries: A Comprehensive Review on Research Progress and Cell Chemistry

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Fluoroethylene Carbonate as an Important Component for the Formation of an Effective Solid Electrolyte Interphase on Anodes and Cathodes for Advanced Li-Ion Batteries

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ACS ENERGY LETTERS (2017)

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An Analogous Periodic Law for Strong Anchoring of Polysulfides on Polar Hosts in Lithium Sulfur Batteries: S- or Li-Binding on First-Row Transition-Metal Sulfides?

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More Reliable Lithium-Sulfur Batteries: Status, Solutions and Prospects

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Stable Na plating/stripping electrochemistry realized by a 3D Cu current collector with thin nanowires

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Two-dimensional vermiculite separator for lithium sulfur batteries

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CHINESE CHEMICAL LETTERS (2017)

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A Compact Nanoconfined Sulfur Cathode for High-Performance Lithium-Sulfur Batteries

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Single-Atom Electrocatalysts

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Ultrafine Silver Nanoparticles for Seeded Lithium Deposition toward Stable Lithium Metal Anode

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Processable and Moldable Sodium-Metal Anodes

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A review of flexible lithium-sulfur and analogous alkali metal-chalcogen rechargeable batteries

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Lithium Bond Chemistry in Lithium-Sulfur Batteries

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Sodium-ion batteries: present and future

Jang-Yeon Hwang et al.

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Highly Stable Sodium Batteries Enabled by Functional Ionic Polymer Membranes

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A Fluorinated Ether Electrolyte Enabled High Performance Prelithiated Graphite/Sulfur Batteries

Shuru Chen et al.

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Confirming reversible Al3+ storage mechanism through intercalation of Al3+ into V2O5 nanowires in a rechargeable aluminum battery

Sichen Gu et al.

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Lithium difluoro(oxalato)borate as an additive to suppress the aluminum corrosion in lithium bis(fluorosulfony)imide-based nonaqueous carbonate electrolyte

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Towards a calcium-based rechargeable battery

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Rational Integration of Polypropylene/Graphene Oxide/Nafion as Ternary-Layered Separator to Retard the Shuttle of Polysulfi des for Lithium-Sulfur Batteries

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Ultrafine TiO2 Decorated Carbon Nanofibers as Multifunctional Interlayer for High-Performance Lithium-Sulfur Battery

Gemeng Liang et al.

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A Cooperative Interface for Highly Efficient Lithium-Sulfur Batteries

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Chemical Dealloying Derived 3D Porous Current Collector for Li Metal Anodes

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A Rechargeable Al/S Battery with an Ionic-Liquid Electrolyte

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Recent advances in transition metal phosphide nanomaterials: synthesis and applications in hydrogen evolution reaction

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A novel synergistic composite with multi-functional effects for high-performance Li-S batteries

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The critical role of lithium nitrate in the gas evolution of lithium-sulfur batteries

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A new finding on the role of LiNO3 in lithium-sulfur battery

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Achieving High-Performance Room-Temperature Sodium Sulfur Batteries With S@Interconnected Mesoporous Carbon Hollow Nanospheres

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Stabilizing Lithium Metal Anodes by Uniform Li-Ion Flux Distribution in Nanochannel Confinement

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Na Reactivity toward Carbonate-Based Electrolytes: The Effect of FEC as Additive

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Powering Lithium-Sulfur Battery Performance by Propelling Polysulfide Redox at Sulfiphilic Hosts

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NANO LETTERS (2016)

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Freestanding three-dimensional core-shell nanoarrays for lithium-ion battery anodes

Guoqiang Tan et al.

NATURE COMMUNICATIONS (2016)

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Avoiding short circuits from zinc metal dendrites in anode by backside-plating configuration

Shougo Higashi et al.

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Hard Carbon Anodes and Novel Electrolytes for Long-Cycle-Life Room Temperature Sodium-Sulfur Full Cell Batteries

M. Kohl et al.

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In situ Microscopic Observation of Sodium Deposition/Dissolution on Sodium Electrode

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A nitrogen doped carbonized metal-organic framework for high stability room temperature sodium-sulfur batteries

Yu-Ming Chen et al.

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Transition Metal Carbides and Nitrides in Energy Storage and Conversion

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A flexible S1-xSex@ porous carbon nanofibers (x≤0.1) thin film with high performance for Li-S batteries and room- temperature Na-S batteries

Linchao Zeng et al.

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Confined Sulfur in Microporous Carbon Renders Superior Cycling Stability in Li/S Batteries

Yunhua Xu et al.

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Hollow Carbon Nanofibers Filled with MnO2 Nanosheets as Efficient Sulfur Hosts for Lithium-Sulfur Batteries

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Porous nitrogen doped carbon foam with excellent resilience for self-supported oxygen reduction catalyst

Hua Zhang et al.

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Fluoroethylene carbonate as an important component in organic carbonate electrolyte solutions for lithium sulfur batteries

E. Markevich et al.

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A novel non-aqueous aluminum sulfur battery

Gil Cohn et al.

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Room temperature rechargeable magnesium batteries with sulfur-containing composite cathodes prepared from elemental sulfur and bis(alkenyl) compound having a cyclic or linear ether unit

Kanae Itaoka et al.

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Electrochemical (De)Lithiation of 1D Sulfur Chains in Li-S Batteries: A Model System Study

Chun-Peng Yang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

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Direct Observation of Sulfur Radicals as Reaction Media in Lithium Sulfur Batteries

Qiang Wang et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2015)

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Pie-like electrode design for high-energy density lithium-sulfur batteries

Zhen Li et al.

NATURE COMMUNICATIONS (2015)

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Long-life Li/polysulphide batteries with high sulphur loading enabled by lightweight three-dimensional nitrogen/sulphur-codoped graphene sponge

Guangmin Zhou et al.

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Accommodating lithium into 3D current collectors with a submicron skeleton towards long-life lithium metal anodes

Chun-Peng Yang et al.

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Novel Large-Scale Synthesis of a C/S Nanocomposite with Mixed Conducting Networks through a Spray Drying Approach for Li-S Batteries

Jie Ma et al.

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Lithium-Sulfur Cells: The Gap between the State-of-the-Art and the Requirements for High Energy Battery Cells

Markus Hagen et al.

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Recent Advances in Electrolytes for Lithium-Sulfur Batteries

Shiguo Zhang et al.

ADVANCED ENERGY MATERIALS (2015)

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Electrocatalysis of Lithium Polysulfides: Current Collectors as Electrodes in Li/S Battery Configuration

Ganguli Babu et al.

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Anion-effects on electrochemical properties of ionic liquid electrolytes for rechargeable aluminum batteries

Huali Wang et al.

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Binder-Free V2O5 Cathode for Greener Rechargeable Aluminum Battery

Huali Wang et al.

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Lithium Iodide as a Promising Electrolyte Additive for Lithium-Sulfur Batteries: Mechanisms of Performance Enhancement

Feixiang Wu et al.

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Quantitative Chromatographic Determination of Dissolved Elemental Sulfur in the Non-Aqueous Electrolyte for Lithium-Sulfur Batteries

Dong Zheng et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2015)

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In Situ Formation of Protective Coatings on Sulfur Cathodes in Lithium Batteries with LiFSI-Based Organic Electrolytes

Hyea Kim et al.

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An Effective Approach To Protect Lithium Anode and Improve Cycle Performance for Li-S Batteries

Feng Wu et al.

ACS APPLIED MATERIALS & INTERFACES (2014)

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Nanoarchitectured Graphene/CNT@Porous Carbon with Extraordinary Electrical Conductivity and Interconnected Micro/Mesopores for Lithium- Sulfur Batteries

Hong-Jie Peng et al.

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A new phenomenon in sodium batteries: Voltage step due to solvent interaction

Ashish Rudola et al.

ELECTROCHEMISTRY COMMUNICATIONS (2014)

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Lithium metal anodes for rechargeable batteries

Wu Xu et al.

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Potassium-Sulfur Batteries: A New Member of Room-Temperature Rechargeable Metal-Sulfur Batteries

Qing Zhao et al.

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Ab Initio Structure Search and in Situ 7Li NMR Studies of Discharge Products in the Li-S Battery System

Kimberly A. See et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

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Effect of Current Density on Morphology of Lithium Electrodeposited in Ionic Liquid-Based Electrolytes

Hikaru Sano et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2014)

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Lithium-sulfur batteries

Linda F. Nazar et al.

MRS BULLETIN (2014)

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Lewis Acid-Base Interactions between Polysulfides and Metal Organic Framework in Lithium Sulfur Batteries

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Liquid-metal electrode to enable ultra-low temperature sodium-beta alumina batteries for renewable energy storage

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Insight into the Electrode Mechanism in Lithium-Sulfur Batteries with Ordered Microporous Carbon Confined Sulfur as the Cathode

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Effect of chemical reactivity of polysulfide toward carbonate-based electrolyte on the electrochemical performance of Li-S batteries

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Alternative materials for sodium ion-sulphur batteries

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Effects of Liquid Electrolytes on the Charge-Discharge Performance of Rechargeable Lithium/Sulfur Batteries: Electrochemical and in-Situ X-ray Absorption Spectroscopic Studies

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On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li-Sulfur Batteries

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A highly ordered nanostructured carbon-sulphur cathode for lithium-sulphur batteries

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The effects of current density and amount of discharge on dendrite formation in the lithium powder anode electrode

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Rechargeable lithium/sulfur battery with suitable mixed liquid electrolytes

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Discharge behavior of lithium/sulfur cell with TEGDME based electrolyte at low temperature

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Dendrite short-circuit and fuse effect on Li/polymer/Li cells

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