Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 32, Issue 35, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202204458
Keywords
catalytic conversion of polysulfides; Li-S batteries; multiple immobilization of polysulfides; N-doped carbon nanoflowers; single Mo-N; (4) atoms
Categories
Funding
- Natural Science Foundation of China [51872208, 52072273]
- Zhejiang Provincial Special Support Program for High-level Talents [2019R52042]
Ask authors/readers for more resources
This study presents a simple and effective strategy for high-performance lithium-sulfur batteries by introducing single Mo-N-4 atoms into N-doped carbon nano-flower matrix as sulfur hosts. Experimental and theoretical evidences demonstrate that these single atoms can regulate the characteristics of sulfur and improve the cycling and rate performance of the batteries.
Rational design of sulfur hosts for effectively confining lithium polysulfides (LiPS) and optimizing the sluggish sulfur kinetics is still a major challenge in lithium-sulfur batteries (LSBs). In this work, a simple strategy of introducing single Mo-N-4 atoms into N-doped carbon nano-flower matrix (Mo-N-CNF) as sulfur host cathode materials is developed to realize high-performance LSBs. These single Mo-N-4 atoms have been demonstrated to regulate the hydrophilic nature, Li-ion diffusion, adsorption capacity, and catalytic conversion of polysulfides via experimental evidences and theoretical calculations. The resulting Mo-N-CNF with high loading content of sulfur (>72 wt.%) exhibits a high specific capacity (1248 mAh g(-1) at 0.2 C) and excellent rate capability (715 mAh g(-1) at 5 C). More importantly, the outstanding cycling performance with a low attenuation rate of only 0.004% per cycle over 400 cycles at 4.27 mA cm(-2) is achieved with the area sulfur loading of 5.1 mg cm(-2). This work demonstrates a viable strategy for using single atoms-based carbon materials with high exposed sites as multiple captors for LiPS and an efficient accelerator for sulfur redox kinetics toward next-generation LSBs with boosted electrochemical performance.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available