4.8 Article

Ultrasensitive Ferroelectric Semiconductor Phototransistors for Photon-Level Detection

Journal

ADVANCED FUNCTIONAL MATERIALS
Volume 32, Issue 36, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202205468

Keywords

ferroelectric semiconductors; optoelectronic memory; photon-level detection; phototransistors

Funding

  1. National Key R&D Program of China [2018YFA0703700, 2021YFA1201500]
  2. National Natural Science Foundation of China [91964203, 61974036]
  3. Strategic Priority Research Program of Chinese Academy of Sciences [XDB44000000, XDB30000000]
  4. CAS Key Laboratory of Nanosystem and Hierarchical Fabrication
  5. Fundamental Research Funds for the Central Universities
  6. Research Funds of Renmin University of China [21XNLG27]
  7. Youth Innovation Promotion Association CAS

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This study demonstrates a low-light-level phototransistor that utilizes a photo-induced ferroelectric reversal mechanism, achieving record-breaking performance and offering potential applications.
Low-light-level photodetections are highly desired in the fields of astronomy and quantum information. However, the existing techniques suffer from high operation voltages and complexity of fabrication, which reduces its compatibility with complementary metal oxide semiconductors (CMOS) based read-out circuit and prevent the use of imaging. Here, a low-light-level phototransistor that employs a photo-induced ferroelectric reversal mechanism in a ferroelectric semiconductor channel: alpha-In2Se3 is demonstrated. It shows a record-low noise-equivalent power of 7.9 x 10(-22) W Hz(-1/2), a record-high specific detectivity of 6.34 x 10(17) Jones, and sensitivity approaching 20 photons in a photon-counting mode, and fast time response of 260 mu s/50 ns in the rise/decay period. It also works as an optoelectronic memory with an on/off ratio of 2.9 x 10(5), retention of longer than 10 years, and endurance of more than 10(6) cycles. Due to its high performance, simple architecture, and small operation voltage, the phototransistor provides a feasible platform for new-generation low-light-level image sensors.

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