4.8 Article

Design of the Thermal Restructured Carbon-Inorganic Composite Aerogel for Efficient Thermal Protection of Aero-Engines

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 14, Issue 33, Pages 38185-38195

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.2c09891

Keywords

composite aerogel; thermal protection; thermochemical restructure; heat insulation; cooling effectiveness; thermal stability

Funding

  1. National Natural Science Foundation of China [52006149, 51806206]
  2. Supercomputing Center in University of Science and Technology of China

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This study designs a carbon-SiO2-Al2O3 composite aerogel with better adhesion property, thermal stability, and heat insulation ability through thermochemical restructuring. The compressive strain-stress test and microscopy observations confirm the structural stability and thermal stability of the composite aerogel, which exhibits superior heat insulation performance. Numerical simulations validate its thermal protection effect.
The heat insulation ability and thermal stability of thermal protection materials play extremely important role in the thermal protection of aero-engines under high temperature. Herein, we design the carbon-SioO(2)-Al2O3 (CSA) composite aerogel through thermochemical restructuring from the phenolformaldehyde resin-SiO2-Al2O3 (PSA) composite aerogel. This thermochemical restructured aerogel not only shows better adhesion property under room temperature but also possesses higher thermal stability and desirable heat insulation ability under high temperature. Taking the PSA-0.5 composite aerogel as an example, the compressive strain-stress test unveils that it can be compressed by 66% without catastrophic collapse, which is beneficial for the adhesion with the metallic matrix. Meanwhile, the transmission electron microscopy and scanning electron microscopy images exhibit the unbroken three-dimensional structure for the CSA-0.S composite aerogel, which confirmed the structural stability of the composite aerogel after thermochemical restructuring. The thermal cycle test indicates that the weight loss of the CSA-0.S composite aerogel is only ca. 8%, firmly confirming its thermal stability. Importantly, the thermal conductivity of the CSA-0.S composite aerogel ranges from 0.024 to 0.083 W m(-1) K-1, indicating the superior performance of heat insulation. Moreover, the numerical simulation is carried out to validate the thermal protection effect of the CSA-0.5 composite aerogel as a thermal protection layer. Together with laminated cooling, it could enhance the surface cooling effectiveness of the metallic matrix to above 0.8. Briefly, this work paves a new pathway for efficient thermal protection materials of aero-engines via the rational design of the thermochemical restructured composite aerogel under the guidance of ANSYS numerical simulations.

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