4.8 Article

Scalable-Manufactured Metamaterials for Simultaneous Visible Transmission, Infrared Reflection, and Microwave Absorption

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 14, Issue 29, Pages 33933-33943

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.2c03346

Keywords

multispectral manipulation; visible transparency; infrared camouflage; microwave absorption; ultrathin metal

Funding

  1. National Natural Science Foundation of China [61875209, 12174209]
  2. Natural Science Foundation of Zhejiang Province [LY19F040003]
  3. Ningbo Key Laboratory of Silicon and Organic T h i n Fi l m Optoelectronic Technologies
  4. Notes

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This study demonstrates a standalone and scalable-manufactured multispectral metamaterial with simultaneous visible transmission, infrared reflection, and microwave absorption capabilities. The prepared material exhibits deep-subwavelength thickness, high visible transmittance, low infrared emissivity, and high microwave absorptance.
Scalable manufacturing of metamaterials with multispectral manipulation capabilities remains highly challenging, which was generally circumvented by integrating several single-spectral metamaterials, potentially leading to complex processes, large thicknesses, and limited fabrication size. We experimentally demonstrate a standalone and scalable-manufactured multispectral metamaterial featuring simultaneous visible transmission, infrared reflection, and microwave absorption. The prepared multispectral metamaterial with an area of 255 cm2 exhibits a visible transmittance of 74.5% at wavelengths of 400-700 nm (the highest 80.2% at 510 nm), a thermal emissivity of 0.08 at the infrared (IR) wavelengths of 2.5-20 mu m (the lowest 0.03 at 19.5 mu m), and a microwave absorptance of 63.4% at frequencies of 8.2-12.4 GHz (the near-perfect 97.4% at 11.5 GHz) on average with a deep-subwavelength thickness of lambda/47. The deep-subwavelength multispectral metamaterial consists of a submillimeter-thick polyethylene terephthalate dielectric spacer sandwiched by a patterned ultrathin metal and a metal mesh back-reflector with ultralow sheet resistances. Unlike the conventional optically transparent microwave absorbers made from indium tin oxides, the surface plasmonic modes can be excited within the submillimeter-thick multispectral metamaterial, bringing about the gap plasmon polaritons-induced microwave attenuation, together with the excellent visible transparency and high IR reflection/low IR emissivity. This work may inspire the designs and practical production of standalone multispectral metamaterials and benefit the protection against ubiquitous IR and microwave reconnaissance without impeding visual observation.

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