Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 145, Issue 18, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.4967405
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Funding
- Austrian Science Fund (FWF) [I978, P26635]
- COST Action [CM1405]
- Austrian Science Fund (FWF) [I978, P26635] Funding Source: Austrian Science Fund (FWF)
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Alkali metal atoms and small alkali clusters are classic heliophobes and when in contact with liquid helium they reside in a dimple on the surface. Here we show that alkalis can be induced to submerge into liquid helium when a highly polarizable co-solute, C-60, is added to a helium nanodroplet. Evidence is presented that shows that all sodium clusters, and probably single Na atoms, enter the helium droplet in the presence of C-60. Even clusters of cesium, an extreme heliophobe, dissolve in liquid helium when C-60 is added. The sole exception is atomic Cs, which remains at the surface. Published by AIP Publishing.
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