Electrochemical CO2 reduction - The macroscopic world of electrode design, reactor concepts & economic aspects

For the efficient electrochemical conversion of CO2 into valuable chemical feedstocks, a well-coordinated interaction of all electrolyzer compartments is required. In addition to the catalyst, whose role is described in detail in the part ``Electrochemical CO2 Reduction toward Multicarbon Alcohols - The Microscopic World of Catalysts & Process Conditions'' of this divided review, the general cell setups, design and manufacture of the electrodes, membranes used, and process parameters must be optimally matched. The authors' goal is to provide a comprehensive review of the current literature on how these aspects affect the overall performance of CO2 electrolysis. To be economically competitive as an overall process, the framework conditions, i.e., CO2 supply and reaction product treatment must also be considered. If the key indicators for current density, selectivity, cell voltage, and lifetime of a CO2 electrolyzer mentioned in the technoeconomic consideration of this review are met, electrochemical CO2 reduction can make a valuable contribution to the creation of closed carbon cycles and to a sustainable energy economy.

Automated summary

Efficient electrochemical conversion of CO2 into valuable chemical feedstocks requires well-coordinated interaction of all electrolyzer compartments, optimal matching of catalyst, cell setups, electrode design, membrane usage, and process parameters. This review aims to comprehensively summarize the current literature on how these aspects affect the overall performance of CO2 electrolysis and highlights the importance of CO2 supply and reaction product treatment for economic competitiveness and sustainable energy economy.