4.6 Article

Ionic liquids: Implementing objectives of sustainability for the next generation chemical processes and industrial applications

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DOI: 10.1016/j.cogsc.2022.100625

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ILs as design tools have unique properties for the next generation chemical processes. This review evaluates the environmental, economic, and social criteria through comparing liquid alkylation technologies and man-made cellulose fiber production.
The unique properties of ionic liquids (ILs) make them an excellent design tool for the next generations of chemical processes. This review covers important impact categories that allow comparison of two scaled-up processes based on ILs: the recently commercialized liquid alkylation technologies and the production of man-made cellulose fibers, which is currently on the brink of commercialization. These technolo-gies are reviewed with emphasis on the environmental, eco-nomic, and social criteria for sustainability. While the first case is an example of ILs that do not just improve conventional processes but also allow the development of disruptive, transformative technologies, the second case raises questions related to IL instability, current recycling difficulties associated with quality of the recycled solvent, synthetic strategy for the superbase ILs, the degradation of ILs in ecosystems, and the IL cost on a multi-ton scale.

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