Journal
SOLAR RRL
Volume 6, Issue 8, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/solr.202200256
Keywords
CZTSSe solar cells; decomposition; defects; interface recombination; Sn-vapor
Funding
- National Natural Science Foundation of China [61574057, 61874045]
- Future Scientist and Outstanding Scholar Cultivation Program of ECNU [WLKXJ202002]
- Fundamental Research Funds for the Central Universities
- ECNU Public Platform for Innovation [004]
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The method of inhibiting the decomposition of CZTSSe solar cells by providing Sn vapor is studied, and it is found that this method can significantly improve the performance of the cells. By inhibiting the decomposition, the interface defects are reduced and the recombination activation energy in the depletion region is improved.
Cu2ZnSn(S,Se)(4) (CZTSSe) solar cells, which are emerging as promising photo-voltaic devices, are currently suffering serious issues of large open-circuit voltage deficit and low fill factor. Decomposition of CZTSSe is one of many factors limiting the efficiency improvement of CZTSSe solar cells, which can lead to the deviation of the chemical environment during the synthesis of CZTSSe. Herein, the Sn-vapor is provided during the synthesis of CZTSSe to inhibit the decomposition, and the effect of decomposition on the intrinsic defects and interface recombination are systematically investigated. The high-quality CZTSSe without the secondary phase and with the low Zn-Sn and Cu-Zn acceptor defects density is obtained. By inhibiting the decomposition, the recombination activation energy at depletion region is improved and the interface defect density is dramatically decreased, indicating the interface recombination is effectively reduced. Consequently, the performance of CZTSSe thin film solar cells, especially the open-circuit voltage and fill factor, has been significantly improved. Finally, based on the excellent CZTSSe film, a photovoltaic device with 12.03% efficiency (active area efficiency is 12.96%) is prepared. These encouraging results provide a new route to controlling the defects and interface recombination of CZTSSe solar cells.
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