4.8 Article

Single-atom catalysts for next-generation rechargeable batteries and fuel cells

Journal

ENERGY STORAGE MATERIALS
Volume 45, Issue -, Pages 301-322

Publisher

ELSEVIER
DOI: 10.1016/j.ensm.2021.11.049

Keywords

Fuel cells; Rechargeable batteries; Zn-CO(2 )battery; Metal-air battery; SACs; Metal-sulfur battery

Funding

  1. Chinese Academy of Sciences Presidents International Fellowship Initiative [2020PS0011]
  2. higher Education Commission of Pakistan via IPFP grant at the Institute of Chemistry, The Islamia University of Bahawalpur, Pakistan

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The worldwide emission of greenhouse gases has sparked increased research interest in sustainable energy conversion and storage devices. Single-atom catalysts (SACs) as electrode materials have shown potential and play a role in solving the bottleneck problems of next-generation energy storage systems.
The worldwide emission of greenhouse gasses combined with the lessening of crude oils is passionate about the research on sustainable energy conversion and storage devices. Further, the fast evolution of flexible and wearable opto-electronic systems, superior reliability, and ultra-long cycling lives of energy storage devices are of great importance. The poor kinetics of small reactions involved in next-generation energy devices are the main obstacles. The required electrode materials for these devices are emerging tasks for the betterment of these devices. Currently, single-atom catalysts (SACs) have gained pronounced interest as emerging and potential applicants as electrode materials for fruitful results. Herein, we have discussed the recent design principles for the fabrication of SACs for rechargeable batteries (Metal-air battery (Metal = Zn, Al, Li), Metal-sulfur battery, (Metal = Na, Li) and Metal-CO 2 battery (Metal = Zn, Li)) and fuel cells. Then, we have summarized the recent advances in assembling and performance of these batteries using SACs as electrode materials. Finally, we have elucidated the role of SACs to resolve the bottle-neck problems of these next-generation energy storage systems. Following the discussion on short-comings and comprehensive future perspectives.

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