Comparative study of effects of natural organic additives and cellulose ether on properties of lime-clay mortars

Admixtures have long been used to improve the performance of lime-based materials. In addition to various natural organic additives, cellulose ethers are widely applied due to their ease of use and reasonable price. In this study, three natural organic additives traditionally used in East Asia (starch, sticky rice, and seaweed pastes) and one type of cellulose ether, specifically hydroxypropyl methylcellulose (HPMC), were compared with respect to their effects on the properties of lime-clay mortar. HPMC and seaweed paste substantially increased the mortar strength by 2.22 and 3.59 times, respectively, whereas starch and sticky rice pastes slightly increased the strength by 1.04 and 1.31 times, respectively. The mechanism of strength improvement can be explained by the type of admixture. HPMC, starch, and sticky rice induce the formation of small calcium carbonate crystals, beneficial for pore refinement due to slow carbonation. Particularly, the remarkable strength enhancement by the cellulose ether is attributed to the fiber-bridging action by cellulose molecules. In the case of seaweed paste, salt species (sodium chloride and sodium alginate), originating from seaweed, act as a carbonation accelerator. Seaweed paste effectively improved various performances (workability, compressive strength, and crack mitigation) of the mortar, while HPMC showed adverse effects on the rest of the performances other than strength.

Automated summary

This study compared the effects of different additives on the properties of lime-clay mortar. Hydroxypropyl methylcellulose and seaweed paste significantly increased the strength of the mortar, while starch and sticky rice paste slightly increased the strength. The mechanisms of strength improvement varied depending on the type of additive.