Journal
ACS OMEGA
Volume 7, Issue 10, Pages 8753-8758Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsomega.1c06983
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Funding
- Sango Monozukuri Foundation
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Semiaromatic polyamides were synthesized by bulk polycondensation, and copolyamides were successfully obtained. The obtained polyamides had high inherent viscosity and good thermal stability, and some copolyamides were suitable for melt-drawing processes.
Semiaromatic polyamides were directly synthesized by bulk polycondensation of aliphatic dicarboxylic acids (with 5, 6, 7, and 10 carbon numbers) and aromatic diamines (4,4'-oxydianiline and 4,4'-diaminodiphenylmethane) under natural pressure. In addition, copolyamides were successfully obtained by the copolymerization of aliphatic dicarboxylic acids, aromatic diamines, and biobased amino acid, 4-aminohydrocinnamic acid. The obtained polyamides had relatively high inherent viscosity values of 0.35-0.76 dL/g. The obtained polyamides exhibited good thermal stability with T-d5% in the range of 316-416 degrees C, even when incorporated with aliphatic methylene units. In particular, some copolyamides (2AO, 2PO, and 2GM) had high T-g values of 150, 158, and 156 degrees C and relatively low T-m values of 277, 288, and 234 degrees C, respectively, which may be preferable thermal properties for melt-drawing processes.
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