Adsorption and Removal of Mercury(II) by a Crosslinked Hyperbranched Polymer Modified via Sulfhydryl

In this study, the highly crosslinked hyperbranched polyamide-amines (H-PAMAMs) were first prepared via one-pot methods and then modified with thiourea to synthesize a novel adsorbent containing sulfhydryl groups (CHAP-SH), which was used to adsorb Hg(II) ions from aqueous solutions. The adsorption characteristics and mechanism of CHAP-SH for Hg(II) ions were systematically studied. As expected, CHAP-SH exhibited a rapid removal performance toward Hg(II), and the maximum adsorption capacity was 282.74 mg/g at 318 K and pH = 4.5. The whole adsorption behavior could be well described by the pseudo-second-order kinetic model and Langmuir and Redlich-Peterson adsorption isotherm models, which reflected that the adsorption process was mainly monolayer chemisorption. Meanwhile, CHAP-SH had strong selectivity for Hg(II) in the presence of multimetal ions, and it had excellent recoverability after five cycles. In order to further elucidate the adsorption mechanism, the adsorbents before and after adsorption were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, thermogravimetric analysis, and energy-dispersive X-ray spectroscopy, and the results showed that the nitrogen-containing, oxygen-containing, and sulfur-containing groups in the adsorbent molecule had synergistic complexation with Hg(II). These results indicated that the adsorbents had great potential in the future treatment of aqueous solutions containing Hg(II).

Automated summary

In this study, a novel adsorbent was synthesized by preparing highly crosslinked hyperbranched polyamide-amines (H-PAMAMs) via one-pot methods and modifying them with thiourea to contain sulfhydryl groups (CHAP-SH). The adsorbent showed rapid removal performance and strong selectivity for Hg(II) ions. The adsorption behavior followed the pseudo-second-order kinetic model and Langmuir and Redlich-Peterson adsorption isotherm models, indicating monolayer chemisorption. Characterization of the adsorbent before and after adsorption revealed synergistic complexation between the nitrogen-, oxygen-, and sulfur-containing groups in the adsorbent molecule and Hg(II).