Conducting polymer based visible light photocatalytic composites for pollutant removal: Progress and prospects

Conducting polymers (CPs) have been proved to be instrumental in enhancing photocatalytic efficacy owing to their unique physicochemical properties and energy levels. In this regard, titanium dioxide (TiO2) has been investigated in transdisciplinary research areas (like catalysis, energy technologies, health, and environment) due to its desirable characteristics. In the process of developing advanced photocatalysts, novel inorganic-organic heterojunction design based materials have been explored and developed in contrast to conventional, inorganic-inorganic type semiconducting photocatalysts (SCPs). In this context, hybrid/composite SCPs comprising CPs and TiO2, have received significant attention for enhancing photocatalytic efficacy in terms of activity as well as visible light activation. The synergistic contribution from CPs (here we focus only on polyaniline (PANI) and polypyrrole (PPy)) and TiO2 have been proved to enhance light-absorption capability in the visible region, photogenerated extraction, and higher stability. Importantly, the published literature (before 2015) on the photocatalysis of TiO2-CP composites mainly discusses in terms of the sensitizing aspects of CP for TiO2. However, there is a critical need to review the literature (beyond 2015) to explore the state of art progress concerning the mechanism of photocatalytic performances as phenomenal parallel developments and knowledge gaps have been addressed on new kinds of heterojunction formation (like S-Scheme over traditional ones), band tuning and interfacial contact effects between two SCPs. In particular, this topical review aims to capture and highlight the current advancements (2016-2021) in relevance to the visible light photocatalytic performance of CP-TiO2 functional composites, which include nanostructures and multi-components. The predominantly available literature over the last five years on the application of CPs-TiO2 functional composites for monitoring or removal of pollutants under visible light activation is reviewed giving importance to revealing the role of CP in concurrent enhancement in both visible light activation and photocatalytic performances. Finally, we elaborate on the challenges and future outlook for advanced research and development in this area. (c) 2022 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

Automated summary

Conducting polymers (CPs) have been proven to play an important role in enhancing photocatalytic efficacy due to their unique physicochemical properties and energy levels. Novel inorganic-organic heterojunction design materials, including hybrid/composite semiconducting photocatalysts (SCPs) comprising CPs and titanium dioxide (TiO2), have received significant attention for their potential in enhancing photocatalytic activity and visible light activation. This topical review aims to highlight the recent advancements (2016-2021) in the visible light photocatalytic performance of CP-TiO2 functional composites, and the role of CPs in improving both visible light activation and photocatalytic performances.