Journal
BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Volume 43, Issue 7, Pages 941-945Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/bkcs.12545
Keywords
alkenoic acids; photoredox reaction; selenolactonization; gamma-lactones
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Funding
- Soonchunhyang University Research Fund
- National Research Foundation of Korea [2021R1A6A1A03039503, NRF-2021-R1I1A3044807]
- National Research Foundation of Korea [2021R1A6A1A03039503] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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A photoredox-catalyzed selenylation and ring closure reaction of alkenoic acid derivatives has been achieved using Rhodamine 6G as an organophotocatalyst under visible light irradiation. The method provides efficient and practical access to structurally diverse selenated gamma-lactones in moderate to high yields.
A photoredox-catalyzed selenylation and ring closure sequences of alkenoic acid derivatives are achieved. This transformation is efficiently accelerated using an inexpensive Rhodamine 6G as an organophotocatalyst under visible light irradiation. The present method affords efficient and practical access to structurally diverse selenated gamma-lactones in moderate to high yields.
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