Data-Driven Machine Learning Intelligent Tools for Predicting Chromium Removal in an Adsorption System

This study investigates chromium removal onto modified maghemite nanoparticles in batch experiments based on a central composite design. The effect of modified maghemite nanoparticles on the adsorptive removal of chromium was quantitatively elucidated by fitting the experimental data using artificial neural network (ANN) and adaptive neuro-fuzzy interference system (ANFIS) modeling approaches. The ANN and ANFIS models, relating the inputs, i.e., pH, adsorbent dose, and initial chromium concentration to the output, i.e., chromium removal efficiency (RE), were developed by comparing the predicted value with that of the experimental values. The RE of chromium ranged from 49.58% to 92.72% under the influence of varying pH (i.e., 2.6-9.4) and adsorbent dose, i.e., 0.8 g/L to 9.2 g/L. The developed ANN model fits the experimental data exceptionally well with correlation coefficients of 1.000 and 0.997 for training and testing, respectively. In addition, the Pearson's Chi-square measure (chi(2)) of 0.0004 and 0.0673 for the ANN and ANFIS models, respectively, indicated the superiority of ANN over ANFIS. However, a small discrepancy in the predictability of the ANFIS model was observed owing to the fuzzy rule-based complexity and overtraining of data. Thus, the developed models can be used for the online prediction of RE onto synthesized maghemite nanoparticles with different sets of input parameters and it can also predict the operational errors in the system.

Automated summary

This study investigates the adsorptive removal of chromium using modified maghemite nanoparticles. Artificial neural network (ANN) and adaptive neuro-fuzzy interference system (ANFIS) modeling approaches were used to quantify the effect of the nanoparticles on chromium removal. The developed ANN model showed excellent fit with the experimental data and outperformed the ANFIS model. The models can be used for online prediction of chromium removal efficiency and detection of operational errors.