4.8 Article

Enhancing strength and ductility via crystalline-amorphous nanoarchitectures in TiZr-based alloys

Journal

SCIENCE ADVANCES
Volume 8, Issue 10, Pages -

Publisher

AMER ASSOC ADVANCEMENT SCIENCE
DOI: 10.1126/sciadv.abm2884

Keywords

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Funding

  1. National Natural Science Foundation of China [52074257, 51771201, 52071124, 52002109, 11772003, 11890681, 11988102]
  2. Natural Science Foundation of Tianjin [20JCZDJC00440]
  3. key project of Natural Science Foundation of Hebei [E2021202135]
  4. National Natural Science Foundation of the Hebei province [E2020202088]
  5. Overseas Scientists Sponsorship Program by Hebei Province [C20210331]
  6. Open Research Fund from the State Key Laboratory of Rolling and Automation, Northeastern University [2020RALKFKT002]
  7. US National Science Foundation [DMR-1611180, 1809640, CMMI-2132336/2132383]

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Crystalline-amorphous composites have the potential to achieve high strength and high ductility. Researchers fabricate a TiZr-based alloy with micrometer-size equiaxed grains that are made up of three-dimensional bicontinuous crystalline-amorphous nanoarchitectures. In situ tension and compression tests reveal enhanced ductility and strain hardening capability, providing ultra-high yield strength, ultimate tensile strength, and large uniform ductility to the alloy. Experiments combined with simulations reveal the synergetic deformation mechanisms, resulting in an effective combination of strength, ductility, and strain hardening.
Crystalline-amorphous composite have the potential to achieve high strength and high ductility through manipulation of their microstructures. Here, we fabricate a TiZr-based alloy with micrometer-size equiaxed grains that are made up of three-dimensional bicontinuous crystalline-amorphous nanoarchitectures (3D-BCAN5). In situ tension and compression tests reveal that the BCANs exhibit enhanced ductility and strain hardening capability compared to both amorphous and crystalline phases, which impart ultra-high yield strength (similar to 1.80 GPa), ultimate tensile strength (similar to 2.3 GPa), and large uniform ductility (similar to 7.0%) into the TiZr-based alloy. Experiments combined with finite element simulations reveal the synergetic deformation mechanisms; i.e., the amorphous phase imposes extra strain hardening to crystalline domains while crystalline domains prevent the premature shear localization in the amorphous phases. These mechanisms endow our material with an effective strength-ductility-strain hardening combination.

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