4.7 Article

Improvement of strength-ductility combination in ultra-high-strength medium-Mn Q&P steel by tailoring the characteristics of martensite/retained austenite constituents

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ELSEVIER
DOI: 10.1016/j.jmrt.2022.02.088

Keywords

Quenching and partitioning; Medium-Mn steel; The CCE-PAG model; M; RA constituents; Mechanical properties

Funding

  1. National Natural Science Foundation of China [51974085, 51674080]
  2. Key R&D Program of Shandong Province [2019TSLH0103]
  3. National Key R&D Program of China [2017YFB0304105, 2017YFB0304400]

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In this study, a low carbon medium-Mn steel was subjected to different quenching and partitioning (Q&P) processes to investigate the influence of fresh martensite and retained austenite constituents (M/RA) on microstructure characteristics and mechanical properties. The study found that the fraction of M/RA decreases with increasing annealing time, and the morphology changes from large-sized blocky islands to fine granular or lath-like shape. A new model, the CCE-PAG model, was proposed to predict the fraction changes and showed better agreement with experimental results compared to the traditional CCE model. The long-time annealed samples exhibited a better combination of strength and ductility, while the short-time annealed samples tended to exhibit brittle fracture.
In this study, a low carbon medium-Mn steel was subjected to different quenching and partitioning (Q&P) processes to investigate fraction and morphology of fresh martensite and retained austenite constituents (M/RA) on microstructure characteristics and me-chanical properties by EPMA, EBSD, TEM and tensile test, etc. By increasing the annealing time, the fraction of M/RA decreases, which gradually evolves from large-sized blocky islands to fine granular or lath-like shape in morphology. This is attributed to the larger-grained prior austenite and the uniform distribution of Mn which reduces the thermal stability of austenite and hence increases the volume fraction of tempered martensite (TM) as well as effectively refining the resultant microstructure. Furthermore, a new CCE-PAG model has been proposed by taking into account the effect of the prior austenite grain size. Compared with the traditional CCE model, the prediction of RA fraction increases first and then decreases with the annealing time, being in better agreement with the experi-mental results. The long-time annealed samples show a better combination of strength and ductility, i.e., their tensile strength reaches ultra-high 1312-1391 MPa, yield strength up to 730-765 MPa, and the elongation is higher than 16%, which results from the existence of large-fractioned TM structure and the sustained TRIP effect. In short-time annealed samples, the crack tends to be initiated and propagated at the edge of coarse M/RA islands, leading to the final brittle fracture. (c) 2022 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

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