4.7 Article

Effect of oxygen on defect states of Al0.4Ga0.6N layers grown by hydride vapor phase epitaxy

Journal

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
Volume 17, Issue -, Pages 1485-1490

Publisher

ELSEVIER
DOI: 10.1016/j.jmrt.2022.01.101

Keywords

AlGaN; Defect states; HVPE; DLTS; Schottky diode; Oxygen effect

Funding

  1. Basic Science Research Program through the National Research Foundation of Korea (NRF)
  2. Ministry of Education [2018R1D1A1B07042909]
  3. NRF
  4. Korean government (MSIT) [NRF-2020R1A4A4078674]

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The defect states and electrical properties of AlxGa1-xN crystals were investigated, and the incorporation of oxygen atoms was found to improve crystal quality and suppress defect states.
The defect states and electrical properties of AlxGa1-xN (x 1/4 0.4) grown by hydride vapor phase epitaxy (HVPE) were investigated. To identify the effect of incorporation of elemental O inAlxGa1-xN crystals, HVPE growth of AlxGa1-xN crystals was conducted with and without the flow of O2. The crystal quality and electrical properties of the AlxGa1-xN layer was analyzed by X-ray diffraction and deep level transient spectroscopy (DLTS). Schottky devices for IeV, CeV and DLTS measurement were formed using Ni/Au metal and Ti/Al metallization. Capacitance DLTS spectra showed two types of deep traps of H1 and H2 in Al0.4Ga0.6N grown without oxygen, while H1' traps were observed in Al0.4Ga0.6N grown with oxygen. All traps were hole-like traps with activation energies of 1.3 eV(H1), 0.59 eV(H2), and 1.2 eV(H1'). These results show that the oxygen atoms can improve the crystal quality and suppress the defect states in AlxGa1-xN crystals. (c) 2022 The Author(s). Published by Elsevier B.V. This is an open access article under the CC

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