Reduced graphene oxide synthesized by a new modified Hummer's method for enhancing thermal and crystallinity properties of Poly(vinylidene fluoride)

A new technique based on the modified Hummer's method to synthesize reduced graphene oxide (rGO) with high purity, as well as enhanced quality and low layer stacking is presented. It aims to demystify traditional considerations made from X-ray diffraction by introducing comprehensive models to determine the number of stacked layers, as well as understand and respect the limit of the physical phenomenon involved in the technique. Poly (vinylidene fluoride) (PVDF) nanocomposites incorporated with up to 5.0 wt.% of rGO were processed via extrusion without using a compatibilizing agent. The results showed that the rGO nanoparticles display a good interface with the PVDF matrix without agglomeration. In addition, there was an improvement in the nanocomposite's stability and thermal resistance. The rGO acted as a nucleating agent, increasing the degree of crystallinity in 33% of the PVDF for all concentrations. The values of water contact angle raised from around 70 degrees in the neat matrix to 80 degrees in the nanocomposite. Scanning electron fractographies demonstrated the tendency of the reinforcement effect of rGO, favoring a greater ductility for cyclical loads. Finally, the results showed that incorporating rGO led to increased nanocomposite thermal performance compared to the neat polymer, revealing a promising candidate for ducts and oil pipelines. (C) 2022 The Authors. Published by Elsevier B.V.

Automated summary

A new technique based on modified Hummer's method is proposed to synthesize high-purity reduced graphene oxide (rGO) with enhanced quality and low layer stacking. The technique incorporates comprehensive models to determine the number of stacked layers and respects the physical limitations involved. The rGO nanoparticles are successfully incorporated into PVDF nanocomposites, resulting in improved stability, thermal resistance, crystallinity, and water contact angle. The reinforcement effect of rGO enhances the ductility of the nanocomposites under cyclic loads. The results demonstrate the promising potential of rGO as a candidate material for ducts and oil pipelines.