Journal
CHEMNANOMAT
Volume 8, Issue 6, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cnma.202200169
Keywords
Plasmonics; Laser Heating; Metal Organic Framework; Composite; Nanoparticles
Categories
Funding
- Deutsche Forschungsgemeinschaft [1580/5-1]
- Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Germany's Excellence Strategy within the Cluster of Excellence PhoenixD [EXC2122]
- Graduiertenakademie of the Leibniz University Hanover
- Hannover School for Nanotechnology
- Konrad-Adenauer-Stiftung (KAS)
- European Research Council (ERC) under the European Union [714429]
- Laboratorium of Nano-and Quantum Engineering
- Projekt DEAL
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This study investigates the heating of gold and gold-zinc oxide nanocrystals in a metal-organic framework using nanosecond laser pulses. The irradiation of Au@ZIF-8 composite particles results in the heating of the gold core and decomposition of the surrounding matrix. The study also shows that the surrounding material can be heated to a distance equivalent to the decomposition of ZIF-8.
Investigations on gold and gold-zinc oxide nanocrystals encapsulated in a matrix of a metal-organic framework (ZIF-8) upon plasmonic heating with nanosecond laser pulses are presented. Irradiation of Au@ZIF-8 composite particles leads to heating of the gold core and decomposition of surrounding matrix acting as temperature probe. Cavities inside the ZIF-8 matrix are found on TEM images after irradiation. Their size is determined dependent on laser energy density and the generated heat at the gold core after absorption of a laser pulse approximated. The surrounding of the gold cores can be heated up to ZIF-8 decomposition over a distance up to 60 nm. This represents a method to visualize heat transfer from the gold cores to the ZIF-8 matrix in three dimensions. Studies on ZIF-8 encapsulated Au@ZnO dot-rod particles give insight in heat transfer between the particle components and show the applicability of the method to different, more complex systems.
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