4.6 Review

Strategies to Improve the Thermoelectric Figure of Merit in Thermoelectric Functional Materials

Journal

FRONTIERS IN CHEMISTRY
Volume 10, Issue -, Pages -

Publisher

FRONTIERS MEDIA SA
DOI: 10.3389/fchem.2022.865281

Keywords

thermoelectric materials; ZT value; seebeck coefficient; electrical conductivity; thermal conductivity

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This paper reviews the design and research progress of thermoelectric materials around lifting ZT value in recent years, discussing the optimization of carrier concentration, improvement of carrier mobility, and the influence of lattice thermal conductivity on thermoelectric performance. The synergistic effect of different dimensions, scales, and crystal structures to reduce lattice thermal conductivity is also discussed, as well as the new application of electro-acoustic decoupling in thermoelectric materials, providing practical ideas for expanding the application and scale industrialization of thermoelectric devices.
In recent years, thermoelectric functional materials have been widely concerned in temperature difference power generation, electric refrigeration and integrated circui, and so on. In this paper, the design and research progress of thermoelectric materials around lifting ZT value in recent years are reviewed. Optimizing the carrier concentration to improve the Seebeck coefficient, the steady improvement of carrier mobility and the influence of energy band engineering on thermoelectric performance are discussed. In addition, the impact of lattice thermal conductivity on ZT value is also significant. We discuss the general law that the synergistic effect of different dimensions, scales, and crystal structures can reduce lattice thermal conductivity, and introduce the new application of electro-acoustic decoupling in thermoelectric materials. Finally, the research of thermoelectric materials is summarized and prospected in the hope of providing practical ideas for expanding the application and scale industrialization of thermoelectric devices.

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