4.6 Review

Hybrid Organic-Inorganic Materials and Interfaces With Mixed Ionic-Electronic Transport Properties: Advances in Experimental and Theoretical Approaches

Journal

FRONTIERS IN CHEMISTRY
Volume 10, Issue -, Pages -

Publisher

FRONTIERS MEDIA SA
DOI: 10.3389/fchem.2022.892013

Keywords

organic-inorganic hybrid; mixed ionic and electronic conducting; sol-gel-alkoxide route; computational modeling; polymer nano composite

Funding

  1. Uruguayan CSIC institution
  2. ANII institution
  3. PEDECIBA institution

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This mini-review provides an updated overview of hybrid organic-inorganic materials, focusing on interface phenomena and transport properties. It reviews preparation techniques, structural features, and computational simulations in this field. The article specifically discusses ionic and electronic transport properties and emphasizes interface phenomena. It also explores mixed ionic-electronic transport properties and provides concluding remarks and perspectives on future research directions.
The main goal of this mini-review is to provide an updated state-of-the-art of the hybrid organic-inorganic materials focusing mainly on interface phenomena involving ionic and electronic transport properties. First, we review the most relevant preparation techniques and the structural features of hybrid organic-inorganic materials prepared by solution-phase reaction of inorganic/organic precursor into organic/inorganic hosts and vapor-phase infiltration of the inorganic precursor into organic hosts and molecular layer deposition of organic precursor onto the inorganic surface. Particular emphasis is given to the advances in joint experimental and theoretical studies discussing diverse types of computational simulations for hybrid-organic materials and interfaces. We make a specific revision on the separately ionic, and electronic transport properties of these hybrid organic-inorganic materials focusing mostly on interface phenomena. Finally, we deepen into mixed ionic-electronic transport properties and provide our concluding remarks and give some perspectives about this growing field of research.

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