Journal
CRYSTALS
Volume 12, Issue 5, Pages -Publisher
MDPI
DOI: 10.3390/cryst12050680
Keywords
azo dyes; nitrogen heterocycles; fluorescence; photoswitchable materials; Zn; Cd; Hg complexes; azoimidazoles
Funding
- Russian Science Foundation [20-73-00094]
- RUDN University Strategic Academic Leadership Program
- Russian Science Foundation [20-73-00094] Funding Source: Russian Science Foundation
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Novel triarylazoimidazoles and their group 12 metal complexes, containing strong electron donors or acceptors, were synthesized and characterized. The complexes exhibited red photo-luminescence emission in solution, and showed antibacterial activity against Gram-positive microorganism S. aureus and Gram-negative microorganism E. coli.
Novel triarylazoimidazoles containing strong electron donors (p-NEt2) or acceptors (p-NO2) by the azoaryl group, and their group 12 metal complexes were synthesized and fully characterized, including X-ray analysis for several complexes. Novel complexes exhibit red photo-luminescence emission (phi up to 0.21) in a solution. Moreover, the antibacterial activity of complexes was tested against Gram-positive microorganism S. aureus and Gram-negative microorganism E. coli.
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