4.7 Article

Electric Energy Storage Effect in Hydrated ZrO2-Nanostructured System

Journal

NANOMATERIALS
Volume 12, Issue 11, Pages -

Publisher

MDPI
DOI: 10.3390/nano12111783

Keywords

zirconium oxide; powder nanotechnologies; nano-ionic capacitors; nanoelectronics; dimensional effects

Funding

  1. H2020/MSCA/RISE/SSHARE [871284]
  2. RO-JINR project [366/2021]
  3. RO-JINR grant [367/2021]
  4. RO-JINR Projects in 2022 within PTP JINR [03-4-1128-2017/2022, 04-4-1143-2021/2025]

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The dimensional effect of electric charge storage was determined for the hydrated ZrO2-nanoparticles system, with a density of up to 270 mu F/g. The study found that the localization of charge carriers occurs at the generalized heterophase boundary-nanoparticles surface. The mechanism of this effect involves the formation of localized electronic states in the nanoparticle material due to donor-acceptor interaction with the adsorption ionic atmosphere. This research is significant for modern nanoelectronics, microsystem technology, and printed electronics.
The dimensional effect of electric charge storage with a density of up to 270 mu F/g by the hydrated ZrO2-nanoparticles system was determined. It was found that the place of localization of different charge carriers is the generalized heterophase boundary-nanoparticles surface. The supposed mechanism of the effect was investigated using the theory of dispersed systems, the band theory, and the theory of contact phenomena in semiconductors, which consists of the formation of localized electronic states in the nanoparticle material due to donor-acceptor interaction with the adsorption ionic atmosphere. The effect is relevant for modern nanoelectronics, microsystem technology, and printed electronics because it allows overcoming the basic physical restrictions on the size, temperature, and operation frequency of the device, caused by leakage currents.

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