Journal
CATALYSTS
Volume 12, Issue 5, Pages -Publisher
MDPI
DOI: 10.3390/catal12050533
Keywords
metal-organic framework; Zr-fumarate-MOF; Ag nanoparticles; nanocatalyst; biodiesel
Categories
Funding
- Deputyship for Research& Innovation, Ministry of Education in Saudi Arabia [DRI-KSU-572]
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Hybrid materials based on metal-organic frameworks and nanoparticles have shown excellent efficiency and synergistic effects in heterogeneous catalysis. In this study, a simple and eco-friendly photocatalytic method was used to fabricate Zr-containing MOF-801 and a silver nanoparticle-based hybrid. The resulting hybrid material served as a highly efficient catalyst for biodiesel production.
Hybrid materials based on metal-organic frameworks (MOFs) and nanoparticles (NPs) have gained considerable popularity in a variety of applications. Particularly, these types of materials have demonstrated excellent efficiency in heterogeneous catalysis due to the synergistic effect between the components. Herein, we report a simple, eco-friendly, photocatalytic method for the fabrication of Zr containing MOF-801 and a silver (Ag) NPs-based hybrid (Ag@MOF-801). In this method, the photocatalytic property of the central metal ion (Zr) of MOF was exploited to promote the formation and deposition of Ag NPs on the surface of the MOF-801 under the irradiation of visible light. The successful incorporation of Ag NPs was ascertained by powder X-ray diffraction (XRD) and UV-Vis analysis, while the morphology and surface area of the sample was determined by N-2 adsorption-desorption and scanning electron microscopy (SEM), respectively. The resulting Ag@MOF-801 hybrid served as a highly efficient catalyst for the transesterification of used vegetable oil (UVO) for the production of biodiesel. The Ag@MOF-801 catalyst exhibited superior catalytic activity compared to its pristine MOF-801 counterpart due to the enhanced surface area of the material.
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