Journal
CATALYSTS
Volume 12, Issue 6, Pages -Publisher
MDPI
DOI: 10.3390/catal12060594
Keywords
perovskite oxide; oxygen evolution; FeOOH; electrocatalyst
Categories
Funding
- National Natural Science Funds of China [21878226]
- Innovative Research Group Project of the National Natural Science Foundation of China [22121004]
- Haihe Laboratory of Sustainable Chemical Transformations [CYZC202107]
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This study proposes a heterostructure composed of LaNiO3 nanorods and FeOOH nanosheets as an electrochemical catalyst for OER. The optimized 0.25Fe-LNO catalyst exhibits a 1D-2D hierarchical structure and shows low overpotential and small Tafel slope. The enhanced performance can be attributed to the synergistic effect between LaNiO3 and FeOOH.
Perovskite-based electrocatalysts with compositional flexibility and tunable electronic structures have emerged as one of the promising non-noble metal candidates for oxygen evolution reaction (OER). Here, we propose a heterostructure comprising perovskite oxide (LaNiO3) nanorods and iron oxide hydroxide (FeOOH) nanosheets as an effective electrochemical catalyst for OER. The optimized 0.25Fe-LNO catalyst with an interesting 1D-2D hierarchical structure shows a low overpotential of 284 mV at 10 mA cm(-2) and a small Tafel slope of 69 mV dec(-1). The enhanced performance can be explained by the synergistic effect between LaNiO3 and FeOOH, resulting in an improved electrochemically active surface area, facilitated charge transfer and the optimized adsorption of OH intermediates.
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