4.5 Article

Study on fractal model of activated carbon for pore formation

Journal

CARBON LETTERS
Volume 32, Issue 3, Pages 863-873

Publisher

SPRINGER JAPAN KK
DOI: 10.1007/s42823-022-00324-y

Keywords

Fractal; Fractal dimension; Activated carbons; Pore-forming mechanism; Pore fractal growth model

Funding

  1. Shaanxi Coal Industry New Energy Technology Co., Ltd. [2020SMHKJ-BK-J-26]

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In this study, a fractal hypothesis with optimized structure was proposed based on the activated carbon pore-forming mechanism, and a pore fractal growth model for the activated carbon activation process was established. The experimental results verified the feasibility of this model.
In view of the activated carbon pore-forming mechanism, the fractal hypothesis of pore interior growth was proposed by optimizing the structure of Sierpinski sponge. Based on the hypothesis and the definition of fractal dimension, the function relationship between the reaction degree, reaction step length, specific surface area and pore volume was deduced, and the pore fractal growth model of activated carbon activation process was established. Semi-coke, apple charcoal and lychee charcoal were used to prepare activated carbon. The pore size distributions of the activated carbons are in accordance with the fractal growth hypothesis. Further, the reaction degree and reaction step length can be determined by the experimental data of pore and surface structure, which verified the feasibility of the pore fractal growth model.

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