4.8 Article

Exceptionally low thermal conductivity realized in the chalcopyrite CuFeS2 via atomic-level lattice engineering

Journal

NANO ENERGY
Volume 94, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.nanoen.2022.106941

Keywords

Thermoelectric; Chalcopyrite; Lattice engineering; Lattice thermal conductivity; Phonon softening

Funding

  1. National Research Foundation of Korea (NRF) - Korean government (MSIT) [NRF-2020R1A2C2011111]
  2. Institute for Basic Science [IBS-R009-G2]
  3. National Natural Science Foundation of China [51872222]
  4. 111 project 2.0 [BP2018008]

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This study introduces a new strategy to control the thermal and charge transport properties of solids by designing desirable defect architecture. By introducing a high concentration of indium to CuFeS2, a stabilized and highly unusual local structure is formed, resulting in a significant reduction in lattice thermal conductivity. This approach achieves one of the highest thermoelectric figures of merit, ZT, among chalcopyrite sulfides.
Designing irregular but desirable atomic arrangements in crystal lattices of solids can greatly change their intrinsic physical properties beyond expectations from common doping and alloying. However, structures of solids are generally determined by thermodynamic preferences during solid-state reactions, strictly restricting delicate atomic-level lattice engineering. Here, we report a new strategy of realizing desirable defect architecture in a highly predictable way to control thermal and charge transport properties of solids. Introducing unusually high concentration indium to the tetragonal chalcopyrite CuFeS2 to form the Cu1-xInxFeS2 (x = 0-0.12) system stabilizes the highly unusual local structure, namely, high-temperature polymorph of cubic zinc blende structure in the surrounding matrix and displaced In+ cation with 5s(2) lone pair electrons from the Cu+ sublattice. This substantially suppresses notoriously high lattice thermal conductivity of tetrahedrally networked CuFeS2 to record-low values -0.79 W m(-1) K-1 at 723 K through multiscale scattering and softening mechanisms of heat carrying phonon, approaching its theoretical lower limit. Consequently, one of the highest thermoelectric figures of merit, ZT, among chalcopyrite sulfides is achieved. Our design principle utilizes standard potentials and ionic radius of constituent elements, thereby readily applicable to designing various classes of solids. Remarkably, we directly imaged the atomic-level structure of positional disorder stabilizing the high-temperature phase and off-centered In+ from the ideal position employing a scanning transmission electron microscope. This observation shows how our material design strategy works, and provides important understanding for how local structures in solids form when either compatible or incompatible atoms are introduced to the crystal lattices.

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