Revisiting the capacity-fading mechanism of P2-type sodium layered oxide cathode materials during high-voltage cycling

P2-type sodium layered oxide cathode (Na2/3Ni1/3Mn2/3O2, P2-NNMO) has attracted great attention as a promising cathode material for sodium ion batteries because of its high specific capacity. However, this material suffers from a rapid capacity fade during high-voltage cycling. Several mechanisms have been proposed to explain the capacity fade, including intragranular fracture caused by the P2-O2 phase transion, surface structural change, and irreversible lattice oxygen release. Here we systematically investigated the morphological, structural, and chemical changes of P2-NNMO during high-voltage cycling using a variety of characterization techniques. It was found that the lattice distortion and crystal-plane buckling induced by the P2-O2 phase transition slowed down the Na-ion transport in the bulk and hindered the extraction of the Na ions. The sluggish kinetics was the main reason in reducing the accessible capacity while other interfacial degradation mechanisms played minor roles. Our results not only enabled a more complete understanding of the capacity-fading mechanism of P2-NNMO but also revealed the underlying correlations between lattice doping and the moderately improved cycle performance. (C)& nbsp;2022 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences Published by Elsevier B.V. All rights reserved.

Automated summary

In this study, the morphological, structural, and chemical changes of P2-NNMO during high-voltage cycling were systematically investigated. It was found that lattice distortion and crystal-plane buckling induced by the P2-O2 phase transition slowed down Na-ion transport and hindered Na-ion extraction. The sluggish kinetics was the main reason for reducing accessible capacity, while other interfacial degradation mechanisms played minor roles.