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Recent Advances in Light-Induced Carboxylation of Organic (Pseudo)Halides with CO2

Journal

ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 11, Issue 8, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.202200207

Keywords

carbon dioxide; carboxylation; photocatalysis; (pseudo)halides; carboxylic acids

Funding

  1. National Natural Science Foundation of China [21871163, 22071134]

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This minireview summarizes the recent development in light-induced carboxylation of organic (pseudo)halides and analogues with CO2 via C-X (X=Br, Cl, O, N, etc.) bond cleavage.
Carbon dioxide is an ideal C1 source in organic synthesis as a precursor for the carboxyl group. With the development of photocatalysis, the carboxylation reactions with CO2 incorporation could be carried out in a more environmental and sustainable manner without the addition of stoichiometric metallic reductants. This minireview summarizes the recent development in light-induced carboxylation of organic (pseudo)halides and analogues with CO2 via C-X (X=Br, Cl, O, N, etc.) bond cleavage.

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