Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 11, Issue 7, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.202200172
Keywords
alkene; alkynylation; catalysis; 1; 3-enyne; ruthenium
Categories
Funding
- National Basic Research Program of China [2015CB856600]
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A ruthenium-catalyzed oxidative cross-coupling reaction of alkenes with triisopropylsilylacetylene was achieved, directed by 2-pyridyl or 2-pyrimidyl groups. This protocol showed good compatibility with various functional groups and exhibited Z-selectivity for the enyne products.
A Ruthenium-catalyzed 2-pyridyl or 2-pyrimidyl directed oxidative cross-coupling reaction of alkenes with triisopropylsilylacetylene was carried out. This protocol suits for mono-, di- and trisubstituted ethenes, as well as various (substituted pyridyl)alkenes and exhibits good compatibility of functional groups and Z-selectivity of the enyne products.
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