Journal
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 10, Issue 9, Pages 3048-3056Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.1c08538
Keywords
long-chain polyamides; nylon; ammonolysis; niobia; depolymerization; recycling
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Funding
- FWO
- KU Leuven
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In this study, a heterogeneous catalytic system based on Nb2O5 was used to depolymerize industrial LCPA samples into α,ω-diamine monomers and oligomers. The catalytic system showed excellent robustness against various contaminants.
Long-chain polyamides (LCPAs) are depolymerized by ammonolysis of the secondary amide bonds into building blocks for new polymer synthesis. Research on the ammonolysis of PA is quite limited and often proposes harsh reaction conditions with homogeneous catalysts. Here, we describe a heterogeneous catalytic system based on Nb2O5. Reactions were performed at a relatively low temperature of 200 degrees C in cyclopentyl methyl ether (CPME) as a green solvent and with limited addition of NH3 and H-2. The ammonolysis of secondary amides was extensively studied, initially with N-hexylhexanamide as a model compound. Since ammonolysis is an equilibrium reaction, it was eventually coupled to a hydrogenation process, with addition of a RuWOx/MgAl2O4 hydrogenation catalyst, in order to achieve complete depolymerization. Industrial LCPA samples were successfully and completely depolymerized to alpha, omega-diamine monomers and oligomers, resulting in product distributions of 62% primary amines and 36% secondary amines. The catalytic system was proven to be very robust against a variety of contaminants, e.g., fillers, other plastics, and additives. Only sulfur-containing compounds poison the Ru-catalyst and have to be removed completely.
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