Study on the Arsenate Removal from Raw As(V)-Rich Wastewater Using Zero-Valent Iron

Due to the large volumes of solid waste produced by the traditional arsenic-rich lime iron salt precipitation method treatment produced during wet-smelting by precious metal workshops, raw As(V)-rich wastewater from a domestic metallurgical enterprise was chosen as the research object. Zero-valent iron (ZVI) was used to remove arsenate (As(V)) from raw wastewater. Factors affecting the adsorption of As(V), such as the ZVI size and adsorption time, were investigated. The As(V) removal percentage was >98.2% when using 40, 100, 250, or 300 mesh ZVI in a 2.8 mg center dot L-1 As(V) solution at pH 7, with an iron mass-wastewater ratio of 5 g/100 mL, and 12 h reaction time. The As(V) removal percentage was >86.5% when using 40 mesh ZVI after 50 min of reaction. A comprehensive evaluation was performed on the effects of factors such as cost and water head loss. Here, 40 mesh ZVI was used for column-based separation, in which the mass of solid waste was very small. Column experiments indicated that the adsorbent more efficiently eliminated arsenate in comparison to the earlier reported adsorbents. High bed volumes (BV) of 3200 BV, 6300 BV, and 8400 BV up to a breakthrough concentration of 100 mu g center dot L-1 were achieved for arsenate removal in the presence of 2.8 mg center dot L-1 of arsenic. The empty bed contact times (EBCTs) were 2.6 min, 5.1 min, and 9.8 min, respectively. Furthermore, the concentrations of other pollutants such as Cu2+, Zn2+, F-, Cd2+, Cr6+, Pb2+, and F- met the national discharge standard. The elimination of As(V) and other heavy metals from solutions employing ZVI is efficient, cheap, and produces no secondary environmental pollution, making it an ideal candidate for heavy metal removal from wastewater.

Automated summary

In this study, a domestic metallurgical enterprise's As(V)-rich wastewater was treated using zero-valent iron (ZVI) to remove arsenate (As(V)). Experimental results showed that ZVI of specific particle size can efficiently remove As(V) from the wastewater, with an arsenate removal percentage of over 98.2%. Column experiments demonstrated that ZVI is more effective in removing arsenate from wastewater compared to other adsorbents, while meeting the national discharge standard for other pollutants. Therefore, ZVI is an ideal candidate for efficient, cost-effective, and environmentally friendly heavy metal removal from wastewater.