Morphology and Properties of Poly(2,6-dimethyl-1,4-phenylene oxide)/Polyamide 11 Hybrid Nanocomposites: Effect of Silica Surface Modification

Poly(2,6-dimethyl-1,4-phenylene oxide)/polyamide 11 (PPO/PA11 80/20) blend filled with neat (SiO2) or modified silica having amine functional groups (A-SiO2) was melt mixing in a twin-screw extruder. The silica was prepared by the sol-gel process. SEM shows that, with increasing A-SiO2 content from 1 to 5 wt.%, the morphology of PPO/PA11blend changed from droplet matrix to co-continuous with phase inversion. The phase inversion was also observed for 5 wt.% of neat silica, but the droplet-matrix structure was retained. The overall rheological and mechanical properties improvement of the A-SiO2-filled composites in comparison with the unfilled blend and neat silica counterpart was drastic, especially in terms of viscosity and stiffness. A-SiO2 improved PPO and PA11 miscibility and reduced the crystallinity of PA11, without affecting the T-c, owing to the compatibilization effect. On the other hand, neat silica slightly increased the crystallinity of PA11 and decreased the crystallization temperature of PA11 and the glass transition temperature of PPO as a result of its plasticization.

Automated summary

The study found that by filling modified silica into PPO/PA11 blends, the rheological and mechanical properties of the composites can be improved. The modified silica can change the morphology of the blends and enhance viscosity and stiffness. On the other hand, neat silica increases the crystallinity of PA11 and decreases the glass transition temperature of PPO.