Journal
ADVANCED ENERGY MATERIALS
Volume 12, Issue 18, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.202103674
Keywords
dual-passivation; interfacial reaction; lattice mismatch; perovskite solar cells; self-assembled small-molecules
Categories
Funding
- National Natural Science Foundation of China (NSFC) [52063019, 51973088, 51833004, U20A20128]
- Double Thousand Plan Science and Technology Innovation High-end Talent Project of Jiangxi Province [jxsq2019201107]
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In this study, the issues of interfacial lattice mismatch and adverse reaction in nickel oxide-based inverted perovskite solar cells are addressed by using a self-assembled small molecule CBSA, achieving high conversion efficiency and excellent stability.
Interfacial lattice mismatch and adverse reaction are the key issues hindering the development of nickel oxide (NiOx)-based inverted perovskite solar cells (PVSCs). Herein, a p-chlorobenzenesulfonic acid (CBSA) self-assembled small-molecule (SASM) is adopted to anchor NiOx and perovskite crystals to endow dual-passivation. The chlorine terminal of SASMs can provide growth sites for perovskite, leading to interfacial strain release. Meanwhile, the sulfonic acid group from SASMs can passivate surface defects of NiOx, conducive to charge carrier extraction. In addition, the self-assembled layer inhibits the adverse interfacial reaction by preventing NiOx contact with perovskite. Therefore, the NiOx/CBSA-based PVSCs obtain a champion power conversion efficiency (PCE) of 21.8%. Of particular note, the unencapsulated devices can retain above 80% of their initial PCE values after storage in a nitrogen atmosphere for 3000 h, in air with a relative humidity of 50-70% for 1000 h, and heating at 85 degrees C for 800 h, respectively.
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