Journal
NATURE COMMUNICATIONS
Volume 13, Issue 1, Pages -Publisher
NATURE PORTFOLIO
DOI: 10.1038/s41467-022-29781-9
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Funding
- China Scholarship Council (CSC) [201906280093]
- Max Planck Society
- National Natural Science Foundation of China [21972110]
- Ghent University BOF doctoral grant [01D04318]
- Research Foundation Flanders (FWO-Vlaanderen) [G000117N]
- UGent concerted action grant [BOFGOA2017000303]
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Chromoselective photocatalysis utilizes sensitizers to convert photon energy into redox potential, allowing for the selection of a specific reaction pathway. In this study, the authors designed two-dimensional amorphous covalent triazine-based frameworks with strong red edge effect for efficient charge separation and photocatalytic bromination reactions.
Chromoselective photocatalysis offers an intriguing opportunity to enable a specific reaction pathway out of a potentially possible multiplicity for a given substrate by using a sensitizer that converts the energy of incident photon into the redox potential of the corresponding magnitude. Several sensitizers possessing different discrete redox potentials (high/low) upon excitation with photons of specific wavelength (short/long) have been reported. Herein, we report design of molecular structures of two-dimensional amorphous covalent triazine-based frameworks (CTFs) possessing intraband states close to the valence band with strong red edge effect (REE). REE enables generation of a continuum of excited sites characterized by their own redox potentials, with the magnitude proportional to the wavelength of incident photons. Separation of charge carriers in such materials depends strongly on the wavelength of incident light and is the primary parameter that defines efficacy of the materials in photocatalytic bromination of electron rich aromatic compounds. In dual Ni-photocatalysis, excitation of electrons from the intraband states to the conduction band of the CTF with 625 nm photons enables selective formation of C-N cross-coupling products from arylhalides and pyrrolidine, while an undesirable dehalogenation process is completely suppressed. Chromoselective catalysis offers an intriguing opportunity to enable a specific reaction pathway in photocatalysis. Here, the authors look into the ability of covalent triazine frameworks to enable the synthesis of different organic compounds by using safer red light instead of harsh UV light.
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