Journal
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume 648, Issue 19, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.202200082
Keywords
Anionic N-Heterocyclic Olefins; Group 4 Metals; Zirconium(II); Reduction; TD-DFT
Categories
Funding
- NSERC of Canada
- Canadian Foundation for Innovation
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Anionic N-heterocyclic olefin (aNHO)-supported Group 4 metal complexes were synthesized through salt metathesis reactions, and a ligand-activated bis-aNHO Zr(II) complex was obtained and structurally characterized.
The synthesis of anionic N-heterocyclic olefin (aNHO)-supported Group 4 metal complexes was achieved by salt metathesis reactions between a lithiated aNHO and Group 4 metal tetrahalides. A ligand-activated bis-aNHO Zr(II) complex was also obtained and structurally characterized.
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