4.4 Article

Development of anti-corrosion properties using ternary electrodeposited Zn-Ni-Co alloys from acidic electrolyte for automobile applications

Journal

TRANSACTIONS OF THE INSTITUTE OF METAL FINISHING
Volume 100, Issue 2, Pages 111-116

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/00202967.2021.2022868

Keywords

Electrodeposition; ternary alloy; Zn-Ni-Co deposit; Tafel polarisation; corrosion resistance; electrochemical impedance spectroscopy

Funding

  1. Science and Engineering Research Board [ECR/2017/001156]

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In this study, a deposition process was designed to prepare ternary Zn-Ni-Co alloy material with good surface quality and corrosion resistance properties on a mild steel substrate. The quality of coatings was optimized through different experimental conditions and parameters. The electrochemical tests showed that the alloy deposited with the highest corrosion resistance property at a practical current density, making it suitable for machinery parts in the automobile industry.
In the present work, the authors designed a deposition process and prepared ternary Zn-Ni-Co alloy material over a mild steel substrate via direct current deposition using an acidic electrolyte for the development of good surface quality and corrosion resistance properties in metal finishing uses. The quality of coatings has been optimised, through implementation of different experimental conditions and parameters, respectively. The prepared specimens have been subjected to X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) with energy-dispersive X-ray spectroscopy (EDS). The XRD pattern revealed highly crystalline properties and FESEM revealed a bright and uniform deposit distribution with an aggregated spherical structure. Electrochemical studies through Tafel polarisation testing and electrochemical impedance spectroscopy (EIS) were carried out in 3.5% NaCl solution. The Tafel analysis revealed that Zn-Ni-Co alloy deposited with the highest corrosion resistance property was observed at a practical currect density of 1 A dm(-2). Thus, it can be possible to produce coated material for good corrosion resistance for machinery parts in automobile industries.

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