4.4 Article

Rapid thermal sintering of screen-printed LiCoO2 films

Journal

THIN SOLID FILMS
Volume 749, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.tsf.2022.139177

Keywords

Lithium cobalt oxide; Screen printing; Photonic sintering; Steel substrate; Rapid thermal processing

Funding

  1. German Federal Ministry for Economic Affairs and Energy (BMWI) [FKZ: 03ETE016F]

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A rapid photonic sintering process was used to obtain compact films of cathode active material of lithium batteries. The films showed homogeneous densification and structural consistency, and exhibited good electrochemical activity.
A rapid photonic sintering process (rapid thermal processing) was used to obtain compact films of cathode active material of lithium batteries. LiCoO2 (LCO) thick films were screen-printed on a steel substrate followed by a contactless thermal processing at 1000 degrees C in only 90 s. A homogenous densification of such layers could be verified by scanning electron microscopy, while the structural consistency of the LCO phase in these layers could be detected by X-ray diffraction and Raman spectroscopy. Furthermore, electrochemical activity of the layer was confirmed by electrochemical cell tests with a liquid electrolyte.

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