4.4 Article

The layered growth and thermoelectric properties of the Mg2Sn films

Journal

THIN SOLID FILMS
Volume 748, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.tsf.2022.139175

Keywords

Thermoelectric material; Magnesium Tin; Thin film; Metal phase; Multi-layered structure; Seebeck coefficient; Resistivity; Sputtering

Funding

  1. National Natural Science Foundation of China [51772193]
  2. Liaoning Revitalization Talents Program [XLYC2008014]

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Mg2Sn films with layered structure were prepared using alternative magnetron sputtering. The phase composition and thermoelectric properties of the films were studied. It was found that the content of metal Mg phase in the films can affect the resistivity and Seebeck coefficient, and films with a small amount of metal Mg phase showed higher Seebeck coefficient and power factor.
The Mg2Sn films with layered structure of a modulation period of 0.5~0.7 mu m thickness, containing a small amount metal Mg phase, were prepared on single crystalline Si substrate using the Mg-Sn alloy target and metal Mg target by alternative magnetron sputtering. The phase composition, surface and cross-section morphology, Xray photoelectron spectroscopy, Hall data and thermoelectric properties of the deposited Mg2Sn films were studied. The results showed that the content of metal Mg phase in deposited Mg2Sn films can be modulated by controlling single sputtering time on metal Mg target. The resistivity and Seebeck coefficient first increase and then decrease with increasing the content of metal Mg phase in deposited Mg2Sn films. The higher Seebeck coefficient and power factor can be obtained when Mg2Sn films contains a small amount of metal Mg phase. It is beneficial to an increase in both Seebeck coefficient and power factor that the deposited films have layered structure.

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