Journal
TETRAHEDRON LETTERS
Volume 100, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2022.153885
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Funding
- JSPS KAKENHI [JP20H03370, JP18H04244]
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A novel cationic copper catalyst was synthesized and found to enhance the Mukaiyama-Aldol reaction, leading to the formation of protected tertiary alcohols.
The [(P+B-P+)CuCl3-](2) complex (P+B-P+ = phosphonium-borate-phosphonium) featuring the dication-monoanion-type counterion was synthesized. The resulting cationic copper catalyst enhanced the Mukaiyama-Aldol reaction of ketene silyl acetals and ketones for the formation of protected tertiary alcohols. (C) 2022 Elsevier Ltd. All rights reserved.
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