Journal
SYNLETT
Volume 33, Issue 11, Pages 1011-1016Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/a-1787-1159
Keywords
photoredox catalysis; Wittig reaction; radical-polar crossover; conjunctive olefination; radical chemistry
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Funding
- Engineering and Physical Sciences Research Council (EPSRC, New Investigator Award) [EP/V006401/1]
- University of Nottingham
- School of Chemistry, University of Nottingham
- Green Chemicals Beacon of Excellence for a Nottingham Research Fellowship
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This article introduces a functional group tolerant and transition-metal-free conjunctive olefination reaction and analyzes its conceptual background and key aspects of development.
We recently discovered a functional group tolerant and transition-metal-free conjunctive olefination reaction with applications in late-stage functionalization chemistry. In this Synpacts contribution, we analyze the conceptual background that has stimulated the discovery of this reactivity and reflect on the key aspects of its development. 1 Introduction 2 Conceptual Background 2.1 Photoredox-Mediated Giese Reaction 2.2 Photoredox Radical-Polar Reactivity 3 The Development of the Process 4 Conclusion
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